Acids and bases Flashcards
Bronsted-Lowry Acid
proton/H+ donor
Base -
proton/ H+ acceptor
Conjugate acid of water
H3O+
Conjugate base of water
OH-
amphiprotic species ….
can be a proton donor or a proton acceptor
A pair of species differing by a single proton is called
a conjugate acid-base pair
amphoteric species …
can act as any kind of acid or base (includes amphiprotic)
Amphoteric oxide
Aluminium oxide (Al2O3)
conjugate base definition
species that is formed when an acid donates a proton
Acid + metal =
salt + hydrogen
Acid + metal hydroxide
= salt + water
Acid + metal carbonate =
salt + carbon dioxide + water
Acid + metal oxide =
salt +water
Acid + hydrogen carbonate
= salt + water + carbon dioxide
Bases without OH-:
NH3
Na2CO3
NaHCO3
why is the pH scale useful?
because it reduces a wide range of numbers to a small range
[H+] (the concentration of hydrogen ions)
= 10^-pH
Equilibrium constant of water (Kw)
= [H+][OH−] = 10^-14
Strong acids ___ ionize
fully
Weak acids ____ ionize
partially
Which has higher conductivity, strong or weak acids?
strong
Which reacts faster, strong or weak acids?
strong
A strong acid has a ____ conjugate base
weak
A strong base has a ____ conjugate acid
weak
natural sources of sulfur oxides
forest fires, volcanoes
natural sources of nitrogen oxides
lightning, bacteria
man-made sources of sulfur oxides
power stations, sulfide smelters
man-made sources of nitrogen oxides
power stations, cars, planes
why is rain naturally acidic?
Mostly due to carbonic acid
carbonic acid equation
CO2 (g) + H2O(l) → H2CO3(aq)
Process by which sulfurous acid is produced in the atmosphere
S(s) + O2(g) → SO2(g)
SO2(g) + H2O(l) → H2SO3(aq)
Process by which sulfuric acid is produced in the atmosphere
S(s) + O2(g) → SO2(g)
SO2(g) + ½O2(g) → SO3(g)
SO3(g) + H2O(l) → H2SO4(aq)
Process by which nitric acid is produced in the atmosphere
4NO2(g) + 2H2O(l) + O2 → 4HNO3
Process by which nitric acid and nitrous acid are produced in the atmosphere
2NO2(g) + H2O(l) → HNO3(aq) nitric acid + HNO2(aq) nitrous acid
A Lewis acid is
an electron pair acceptor
A Lewis base is
an electron pair donor
What distinguishes a strong base from a weak base?
Strong bases fully ionise, weak bases partially ionise
Effects of carbonic acid on the natural world:
Corrodes limestone buildings, acidifies lakes