Acid-Base Equilibrium Systems Flashcards

1
Q

what are acids according to Arrhenius’s theory

A

substances that produce a hydrogen ion when dissolved in water H+

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2
Q

what are bases according to Arrhenius’s theory

A

substances that produce a hydroxide ion when dissolved in water OH

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3
Q

acids based on bronsted lowry

A

molecules or ions that donate a proton (proton donors)

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4
Q

bases based on bronsted lowry

A

molecules or ions that accept a proton (proton acceptors)

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5
Q

what do conjugate pairs mean in terms of acids and bases?

A

an acid becomes a base by losing a proton, and a base becomes an acid by gaining a proton

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6
Q

amphiprotic substances

A

a substance that acts as an acid with a base, and as a base with an acid. molecules that can donate or accept a proton

for example, water is amphiprotic because it can donate or accept a proton within an equation (more specifically, it can turn into H30+ or OH-)

HCO3−, H2PO4–, HSO4–

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7
Q

electrolyte

A

a substance that conducts electricity when it forms ions

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8
Q

the ion product constant of water

A

kw=[H3O+aq][OH-aq]=1.0 times 10^-14

hydronium ion times hydroxide ion equals ones times ten to the exponent negative fourteen

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9
Q

when is a solution acidic?

A

when the hydronium concentration is larger than the hydroxide concentration

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10
Q

when is a solution basic?

A

when the hydroxide concentration is larger than the hydronium concentration

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11
Q

how do you find ph

A

ph concept was introduced by Danish chemist Soren Sorensen in 1909

pH refers to the acid

ph=-log [H3O+}
[H3O+]=10-ph
pH+pOH=14.00 –>pH=14-pOH

ph=-logarithm times the concentration of the hydronium ion

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12
Q

how do you find pOH?

how do you find hydroxide?

A

pOH=-log[OH-]

[OH-]=10-pOH

find the pH then use the formula pH+pOH=14.00

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13
Q

how do strong acids dissociate in water

A

they dissociate completely

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14
Q

how do weak acids dissociate in water

A

they dissociate partially

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15
Q

what are the trends of binary acids in terms of increasing

A

increases from left to right as electronegativity (ability to attract electrons) increases, and from top to bottom as the strength of the bond decreases (it can dissociate easily)

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16
Q

how do you find the acid dissociation constant

A

convert to mols/L using c=n/V
plug into ICE table
Ka=[H3O+] [A]/[HA]

17
Q

how do you find percent dissociation

A

Acid percent dissociation=[H3O+][HAi] times 100

Base percen concentration=[OH-][Bi] times 100

18
Q

how do you find the equilibrium concentration of the ionization of a base

A

Kb=[BH][OH-]/[B]

kw=(Ka) (Kb)

19
Q

what are the trends of oxyacids

A

the strength increases with the number of oxygen atoms found in the acid

HClO (aq), HClO2 (aq), HClO3 (aq). HClO4 the strength increases to the right

20
Q

what is salt?

A

an ionic compound produces as a result of a neutralization reaction of an acid and a base

21
Q

salt hydrolysis

A

when salt reacts with water to produce ions

22
Q

what makes a solution acidic during hydrolysis?

A

when there is a neutralization of a strong acid and a weak base
when the acid overpowers the base during the neutralization reaction

Hydro like water

23
Q

what makes a solution basic during hydrolysis?

A

when the base overpowers the acids when there is a strong base and a weak acid during the neutralization reaction

24
Q

what is a buffer solution?

A

made by mixing a usually a weak acid together with its conjugate base that is strong, and a weak base with its conjugate acid that is strong

a solution that resists change in pH, and its capacity is a pH of 7

25
Q

titration

A

quantitive analysis of neutralization reactions

mixing to make neutralization

is the slow addition of one solution of a known concentration called a titrant to another solution of unknown concentration called a tirand but a known volume until the reaction reaches neutralization, which is indicated by a change in colour

a technique in which one solution is used to analyze another solution

26
Q

indicator

A

weak acids that change colour as the concentration of hydronium ion changes

substances that give a visible sign, usually a change in colour with pH and suggest a chemical reaction has occurred

27
Q

endpoint

A

the physical change in colour when the reaction is complete

when the indicator changes colour

28
Q

equivalence point

A

point in a titration when enough titrant has been added to react with a substance in a solution that is being titrated, when the solution becomes neutral

29
Q

Describe what a strong acid strong base titration graph looks like?

A

graph line starts from the bottom, specifically, a pH of 1, then reaches an equivalence point/neutralization at 7, then goes up to a pH of 12

30
Q

describe the graph of a weak acid strong base titration

A

the graph starts at 3, and reaches equivalence at a pH of 8, above 7 meaning, the solution is basic, then goes up to pH at 12

31
Q

Describe weak base strong acid titration graph

A

the graphs start from the top at a pH of 13, then reach equivalence at a pH of 5, below 7 meaning, the solution is acidic, then goes down to a pH of 2

32
Q

quantitative analysis

A

a scientific approach where raw data is manipulated to give meaningful information

33
Q

what makes a solution basic?

A

with the pH is above 7 for example 8 and there is more hydroxide than hydronium

34
Q

what makes a solution acidic?

A

when the pH is below 7 for example 3 and the concentration of hydronium stronger than the concentration of hydroxide

35
Q

What is the difference between acids, bases, and amphiprotic substances in terms of their molecular formula?

A

for acids, the formula begins with H
for bases, the formula has an OH at the end
for amphiprotic substances the formula has H at the beginning, and O at the end with a negative