Acid and base Flashcards

1
Q

how to dry a solid from aq solution

A
  1. filter the mixture
  2. wash it with DI water
  3. dry in oven
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2
Q

what is standard solution

A

solutions with accurately known concentrations

use to determine concentrations of other reagent

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3
Q

why back titration is needed

A

no suitable indicator
reaction rate is slow
insoluble in water

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4
Q

why its not appropriate to rinse the conical flask with acid

A

Some H+ ions remain in the flask, and more alkali than actually required is used to reach the titration end point.

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5
Q

how to prepare a 250cm3 of standard solution

A

to dissolve the solid by adding deionized water to the solid in a beaker
Transfer the solution with rinsing with deionized water into a 250cm3 volumetric flask and add deionized water until the lower meniscus of water level reaches the graduation mark of the flask.
Shake thoroughly.

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6
Q

how to perform crystallisation

A

Evaporate the filtrate, allow solid crystallize out

Collect crystals and then dry it with a filter paper.

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7
Q

what is alkali

A

Alkali is water soluble substance reacts with acid to give salt and water only

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8
Q

is all acidic compound contain H?

A

no
acidic =/= acid
CO2 SO2 is acidic

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9
Q

what is titrant analyte and titre

A

titrant in burette
analyte in conical flask
titre is the volume/concentration of the solution determined

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10
Q

NH4Cl acidic or alkaline?

A

acidic

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11
Q

XHSO4 acidic or alkaline?

A

acidic

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12
Q

is NaOH/ Na2O a salt

A

no
OH- and O2- are not come from anion of any acid
salt = metal cation or NH4+ + anion formed from acid

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13
Q

what is basicity?

A

basicity of an acid is the maximum number of H+ ion which can be produced from 1 acid molecule / the number of ionizable H atom in one acid molecule

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14
Q

what shd be done when conc acid spill to the skin

A

wash it with running cold water

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15
Q

how to dilute a conc acid

A

add conc acid slowly to a large amount of water with constant stirring

if water is added to conc acid, a lot of heat is released and the heat can cause splashing out of the corrosive acid solution.

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16
Q

difference between drying agent and dehydrating agent

A

drying agent –> physical change (CaO / anhydrous CaCl2)

dehydrating agent –> chemical change (conc H2SO4)

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17
Q

which gas does anhydrous CaCl2 cannot dry

A

NH3

18
Q

why use an inverted funnel when passing HCl gas to water

A

prevent sucking back of water as HCl is soluble in water

19
Q

Na2SO3 acidic or alkaline?

A

alkaline

20
Q

NaHSO3 acidic or alkaline?

A

alkaline

21
Q

why theres no observable change when Ca2+ + NH3

A

OH- concentration too low in NH3

22
Q

why the boiling tube should be tilted downward in an experiment

A

prevent the condensed water from flowing back into the hot boilng tube which would cause cracking of the tube

23
Q

how NH3 can be collected

A

upward delivery as NH3 is less dense than air

or gas syringe (百搭)

24
Q

why cant we use acid when alkali spill to our skin

A

neutralization is highly exothermic

it causes burning of our skin

25
Q

what does the strength of acid depends on?

A

the degree of ionization to form H+

26
Q

what does the strength of alkali depends on?

A

the degree of ionization to form OH-

27
Q

factors that affect the pH of an aicd

A

concentration
strength (strong or weak)
basicity

28
Q

why some soil is acidic

A

acid rain

acidic fertiliser

29
Q

what can be used to neutralise acidic soil

A

CaO CaOH CaCO3
as they are not very soluble in water
so it wont make the soil too alkaline

30
Q

why nitrogen is present in fertiliser

A

nitrogen is required for the formation of amino acid

31
Q

why we should wash the salt prepared with cold DI water

A

to remove any soluble impurity

help reduce the loss of the salt

32
Q

what is volumetric analysis

A

its a method used to determine quantity or concentration of a substance by titration

33
Q

what is requirement of primary standard

A

highly pure
stable in air and solution
does not absorb water or carbon dioxide in air

34
Q

why conc H2SO4 cant be primary standard

A

it absorb water so it cannot weigh out accurately

35
Q

how to prepare a primary standard

A

from a solid

from diluting a more concentrated standard solution

36
Q

titration of solution A against solution B

A or B in burette?

A

B in burette

A in conical flask

37
Q

burette must hold

A

strong acid/ strong alkali

38
Q

how the end point between the neutralization of weak acid and weak alkali be determined

A

measuring the temperature change and plot a graph

39
Q

why diluting chemical in titration

A

to save chemicals

40
Q

what is the state of citric acid in room temperature

A

solid

41
Q

describe the procedure that should be followed when preparing a burette containing HCl

A

rinse the burette with distilled water
then with the hydrochloric acid
fill the burette with the hydrochloric acid, making sure that the space between the tap and the tip of the burette is filled with the acid so there is no air bubbles in the burette
Also, the meniscus should not be above the zero mark