94. Metals & Alloys Flashcards

1
Q

Provide examples of metals used in dentistry.

A
  • PD framework (CoCr, gold);
  • Denture bases (stainless steel);
  • Crowns (stainless steel);
  • Orthodontic appliances (NiTi);
  • Restorations (amalgam).
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2
Q

Why is amalgam different to all other metals used in dentistry?

A

There is a distinct difference that amalgam requires a setting reaction during its use in clinic

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3
Q

What are the properties of interest with regards to choosing a metal?

A
  • Strength;
  • Rigidity;
  • Elastic Limit;
  • Ductility;
  • Hardness.
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4
Q

What are the superior properties of interest with regards to choosing a metal?

A

Strength and rigidity

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5
Q

What is the major disadvantage of using metals in dental appliances?

A

Poor aesthetics

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6
Q

What is the difference between a metal and an alloy with regards to their chemical structure?

A

A metal is an aggregation of a single type of atom in a crystalline structure whereas in an alloy, the crystalline structure combines different metal atoms.

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7
Q

What is elasticity with regards to metals?

A

The maximum stress that can be applied without plastic deformation/ fracturing

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8
Q

What is ductility with regards to metals?

A

The amount of plastic deformation prior to fracture i.e. a measure of the extent a metal can be shaped/ manipulated

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9
Q

What is malleability with regards to metals?

A

The amount of compressive stress/ force a metal can withstand

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10
Q

What determines the crystalline structure of a metal?

A
  • Method of production;

- Shaping e.g. cold working or swaging.

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11
Q

What is a grain?

A

A single atom within the lattice

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12
Q

What is a crystal?

A

Lattice arrangement of atoms

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13
Q

Describe the cooling curve of a pure metal.

A

The cooling curve illustrates the change in temperature, over time as a metal cools from molten to a solid.

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14
Q

What does the plateau on a cooling curve indicate?

A

This shows where all molten metal atoms have changed to a solid. From this point, the temperature of the solid metal gradually decreases.

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15
Q

Describe the crystal growth of a metal.

A
  • A metal forms dendrites around a site of nuclei of crystallisation;
  • Crystals (or grains) grown until the impinge on other crystals;
  • This region is known as a grain boundary.
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16
Q

What are equi-axed grain structure and how do you achieve it during crystal formation?

A

Crystal growth of equal dimension in each direction

17
Q

What is radial grain structure and how do you achieve it during crystal formation?

A

Molten metal cooled quickly in a cylindrical mould

18
Q

What are fibrous grain structure and how do you achieve it during crystal formation?

A

Molten metal pulled through a narrow aperture leading to a fibrous grain, e.g. wire

19
Q

What are the major structural differences between quick and slow cooled metals?

A
  • Quick cooling (quenching), results in more nuclei and small fine grains;
  • Slow cooling results in fewer nuclei and large, coarse grains.
20
Q

What are the major mechanical differences between quick and slow cooled metals?

A

Quick cooled metals have enhanced mechanical properties, which is why manufacturers often add nucleating agents to encourage nucleation of molten metal

21
Q

What mechanical properties are enhanced with quick cooled metals?

A
  • High elastic limit;
  • Increased UTS (tensile strength);
  • Increased hardness.
22
Q

What is a mechanical disadvantage of quenched metals?

A

Decreased ductility

23
Q

What are the factors needed for quenching?

A
  • Small bulk;
  • Heat metal/alloy just above Tm;
  • Mould has to have high thermal conduction e.g. metal bucket;
  • Quickly quenched (bucket into a bucket of cold water).
24
Q

What is a defect or dislocation in a metallic crystal lattice?

A

A misalignment of atoms in the network leading to 2 or more planes of crystallography

25
What happens if a force is applied to the defect?
- Atoms move along the dislocation which results in a different shape of metal; - E.g. 'step change' where the metal no longer has a defect but is now a different shape.
26
What is metal slip?
- Propagation of Dislocations; | - Like a domino effect through the atoms when a force is applied to the defect/ dislocation.
27
How do the presence of defects/ dislocations effect the mechanical properties of metals?
- Increase in elasticity; - Increase in UTS; - Increase in hardness; - Decrease in ductility; - Decrease in impact resistance.
28
What factors impede dislocation movement?
- Grain boundaries (the more boundaries, the less a defect can move to other grains); - Alloys (different atom sizes); - Cold working (dislocations build up at grain boundaries).
29
How does cold working effect the distribution of dislocations in a lattice?
This leads to slip so that dislocations collect at grain boundaries
30
How does the effects of cold working on dislocations effect the metal's mechanical properties?
- Dislocations at grain boundaries; - Stronger, harder (at surface) metal; - Higher elasticity; - Higher UTS; - Lower ductility; - Lower impact strength; - Lower corrosion resistance.
31
What is residual stress?
Stresses that remain in a solid material after the original cause of the stresses has been removed
32
What is the relationship between residual stress and cold working?
The more cold work done to a metal, the more residual stress there is - undesirable
33
Why is residual stress undesirable and how is this overcome in manufacturing of metals?
Residual stress causes instability in the lattice which can lead to distortion over time. This is overcome by annealing.
34
What is the relationship between recrystallisation temperature and cold working?
The greater the amount of cold work done to the metal, the lower the recrystallisation temperature
35
Why should excessive temperature rises be avoided?
Large grains replace smaller, coarse grains leading to poorer mechanical properties