22. Composite Resins Flashcards
L22: What are the ideal mechanical properties of a direct filling material?
- Strength;
- Rigidity;
- Hardness;
- Bonding to tooth/ compatible with bonding systems.
L22: Other than mechanical properties, what other ideal properties are there for direct filling materials?
- Thermal properties;
- Aesthetics;
- Radiopaque (opaque to X-rays);
- Handing/ viscosity;
- Anticariogenic;
- Smooth surface finish/ polishable;
- Low setting shrinkage;
- Biocompatible.
L22: What are the two main constituents of a composite resin?
- Glass filler particles (hard);
- Resin (soft).
L22: Alongside glass filler particles and resin, what else do composite resins contain?
- Camphorquinone (photo initiator);
- Low weight dimethacrylates;
- Silane coupling agent.
L22: Give an example of a type of filler particle:
- Microfine silica;
- Quartz;
- Borosilicate glass;
- Lithium aluminium silicate;
- Barium aluminium silicate.
L22: What is the conventional particle size for filler particles in a composite resin?
10-40 um
L22: What size of filler particles do hybrid composites contain?
A range, 0.01-0.1um and 1-10um
L22: What resin monomers are used in composite resins?
- Bis-GMA;
- Urethane dimethacrylates.
L22: What are the key characteristics of resin monomers in a composite resin?
- Difunctional molecule (C=C bonds, to facilitate cross linking);
- Undergoes free radical addition polymerisation.
L22: How does camphorquinone initiate bonding of composite resin?
- Activated by blue light;
- Produces radical molecules;
- These initiate free radical addition polymerisation of Bis-GMA;
- Changes in resin properties;
- i.e. increased MW, increased viscosity and strength.
L22: What is the role of low weight dimethacrylates?
Improve material - adjust viscosity and reactivity
L22: What is the role of saline coupling agent?
Improve bonding - favours glass-resin bonding
L22: What type of restorations are composites used for?
- Where aesthetics are important;
- Class III, IV and V permanent restorations;
- Class II - limited occlusal wear;
- Labial veneers;
- Inlays, inlays, indirect technique;
- Cores;
- Modified forms as luting cements (some dual cured).
L22: What are the three main classification classes for composite resins?
- Filler type;
- Curing method (light/ self);
- Area of use;
- Handling (condensable, syringeable, flowable).
L22: Sometimes a range of filler particle sizes are used to accommodate composite volume, how does this effect the mechanical properties?
Stronger, harder, more rigid
L22: What other effects does adding filler particles (to fill volumes) have?
- Improved aesthetics;
- Increased abrasion resistance;
- Lower thermal expansion;
- Lower polymerisation shrinkage;
- Less heat of polymerisation;
- Some radiopaque.
L22: What wavelength is blue light (used to cure light-cured composites)?
430-490 nm
L22: Why is a certain wavelength of light used to cure composites?
Absorption peak at ~ 450nm for camphorquinone