9.1 Oxidation and reduction Flashcards

1
Q

what is the current definition of oxidation?

A

loss of electrons

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2
Q

what is the current definition of reduction?

A

gain of electrons

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3
Q

what are the 2 old definitions of oxidation?

A
  1. addition of oxygen
  2. loss of hydrogen
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4
Q

what are the 2 old definitions of reduction?

A
  1. loss of oxygen
  2. gain of hydrogen
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5
Q

why are the old definitions insufficent?

A

not every compound that is oxidized adds or loses oxygen or hydrogen

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6
Q

what is the mnemonic for the definitions of oxidation and reduction?

A

OILRIG
oxidation is the loss of electrons
reduction is the gain of electrons

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7
Q

how is oxidation related to oxidation state?

A

oxidation causes a gain in oxidation state

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8
Q

How is reduction related to oxidation state?

A

reduction causes a reduction/ decrease in oxidation state

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9
Q

what is a redox reaction?

A

a reduction and oxidation reaction, as both occurs at the same time

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10
Q

what are the 5 steps of the Winkler method?

A
  1. saturate water with oxygen
  2. leave for 5 days
  3. add excess manganese (II) salt
  4. add potassium iodide
  5. titrate with sodium thiosulphate
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11
Q

how many moles of dissolved oxygen are found using the Winkler method?

A

1/4 moles of produced iodine or used thiosulphate

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12
Q

what is the conversion of ppm to SI units?

A

1 ppm = 1 mg/dm^3

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13
Q

what is the formula for the concentration of oxygen in ppm?

A

[O2} = mass of oxygen (g)/ volume of oxygen (cm3) x 10^6

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14
Q

what is the formula for BOD?

A

BOD = final [O2] - initial [O2]

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15
Q

what is the difference between oxidation and reduction?

A

oxidation is the loss of electrons and reduction is the gain of electrons

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16
Q

why does oxidation and reduction occur at the same time during a reaction?

A

if a substance is oxidized, it means that the other substance is reduced. therefore, they always occur at the same time

17
Q

—- is an increase in oxidation state

A

oxidation

18
Q

—- is a decrease in oxidation state

A

reduction

19
Q

an —- is a substance that oxidizes another substance and itself undergoes reduction

A

oxidizing agent

20
Q

a —- is a substance that reduced another substance and itself undergoes oxidation

A

reducing agent

21
Q

the —- is the application of redox to measure the biological oxygen demand

A

winkler method

22
Q

the amount of dissolved oxygen required to decompose organic material in water is called the —-

A

biological oxygen demand (BOD)

23
Q

1 mole of produced iodine or used thiosulphate in the winkler method is equal to —-

A

4 times the moles of dissolved oxygen

24
Q

the —- is a table outlining the order of how easily different elements undergo oxidation, which decreases down the list

A

reactivity series