7th Flashcards
carbocation🌷
trivalent carbon
+ charge
unstable
sp2 hybridised
120*
observed in H + C nmr spec
reactive intermediate
how are carbocations stabilised🌷
they crave electron density
groups around them can donate some electron density
to it’s empty P orbital
to help stabilise it
hyperconjugation🌷
sigma bonds from CH
donate electron density
more CH bonds = more stable
order of stability of carbocations
tertiary
secondary
primary
just Hs around it
carbocations can also be stabilised using
conjugation
move the + charge to the end of the molecule??
🌷greater degree of resonance means
greater stability
more number of resonance structures
more stable the molecule becomes
due to less electron electron repulsion
carbocations can also be stabilised by🌷
lone pairs donating electron density
these groups that donated then would then get a + charge.
more substituted alkenes form what type of carbanion🌷
a less stable anion
less acidic
as degree of unsaturation increases why does stability increase and acidity increase🌷
higher degree of unsaturation = hybridisation
sp3 vs sp
sp has more s character and therefore is more stable : closer to nuc and therefore more stable : more acidic
is an anion is more stable,, what does that mean about the h🌷
it’s more acidic
what form of stability makes a hydrogen more acidic due to making it more stable🌷
more acidic = more stable
more acidic and stable bc it’s aromatic: flat, huckels rule, conjugated, cyclic
more conjugation of the anion means🌷
more stable
more acidic
more electronegative atom near an anion means the anion is🌷
more stable
less e- near it
more acidic