7th Flashcards

1
Q

carbocation🌷

A

trivalent carbon
+ charge
unstable
sp2 hybridised
120*
observed in H + C nmr spec
reactive intermediate

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2
Q

how are carbocations stabilised🌷

A

they crave electron density
groups around them can donate some electron density
to it’s empty P orbital
to help stabilise it

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3
Q

hyperconjugation🌷

A

sigma bonds from CH
donate electron density
more CH bonds = more stable

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4
Q

order of stability of carbocations

A

tertiary
secondary
primary
just Hs around it

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5
Q

carbocations can also be stabilised using

A

conjugation
move the + charge to the end of the molecule??

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6
Q

🌷greater degree of resonance means

A

greater stability
more number of resonance structures
more stable the molecule becomes
due to less electron electron repulsion

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7
Q

carbocations can also be stabilised by🌷

A

lone pairs donating electron density
these groups that donated then would then get a + charge.

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8
Q
A
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9
Q

more substituted alkenes form what type of carbanion🌷

A

a less stable anion

less acidic

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10
Q

as degree of unsaturation increases why does stability increase and acidity increase🌷

A

higher degree of unsaturation = hybridisation
sp3 vs sp

sp has more s character and therefore is more stable : closer to nuc and therefore more stable : more acidic

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11
Q

is an anion is more stable,, what does that mean about the h🌷

A

it’s more acidic

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12
Q

what form of stability makes a hydrogen more acidic due to making it more stable🌷

A

more acidic = more stable

more acidic and stable bc it’s aromatic: flat, huckels rule, conjugated, cyclic

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13
Q

more conjugation of the anion means🌷

A

more stable
more acidic

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14
Q

more electronegative atom near an anion means the anion is🌷

A

more stable
less e- near it
more acidic

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