7 Chem Equillibria Flashcards
Reversible reaction
A reaction that can proceed in both the forward and the backward directions
Dynamic equilibrium
A reversible process in a closed system which the rate of forward reaction is equal to the rate of the backward reaction, such that there is no change in the concentrations of products and reactants
Equilibrium Constant
K = [products]^coeff / [reactants]^coeff
Exclude solids (and liquids for pressure constant)
Reaction Quotient
Q = [products]^coeff / [reactants]^coeff
[products]/[reactants] are taken at any given time
Degree of dissociation
Amount of substance dissociated/Initial amount of substance
Le Chatelier’s Principle
If a system at dynamic equilibrium is subjected to a change that disturbs the equilibrium, the system will react in a way to counteract some of the effects of the change
ΔG and equilibrium composition
ΔG = -RT ln K
Haber Process
T: 450°C
p: 250 atm
Catalyst: Finely divided iron