2 Atomic Structure Flashcards
Nucleon number
Total number of protons and neutrons
Proton number
The number of protons
Isotopes
Atoms of the same element with the same number of protons but different number of neutrons
Extent of deflection
Proportional to charge/mass
Orbital
The region of space where there is a high electron density
Degenerate
Same energy
Aufbau Principle
Electrons reside in the orbital of the lowest possible energy first
Pauli Exclusion Principle
An orbital can accommodate a maximum of 2 electrons, and they must be of opposite spins
Hund’s Rule
Electrons occupy degenerate orbitals singly and with the same spin before pairing occurs
Ionization energy
Energy required to remove 1 mole of electrons from 1 mole of gaseous atoms/ions
Nuclear charge
Positive charge of nucleus due to protons
Shielding effect
Valence electron shielded from attraction of the nucleus by the inner principal quantum shell.
Increasing trend of 1st IE across a Period
Nuclear charge increases, negligible increase in shielding effect. Atomic radius decreases
Effective nuclear charge increases
Group 2 to 13 anomaly (Trend of 1st IE)
p electron (Group 13) has higher energy than s electron (Group 2)
Group 15 to 16 anomaly (Trend of 1st IE)
Coulombic repulsion between paired p electrons (Group 16)