6.4 - Weathering And Soil Flashcards
What is the biogeochemical cycle?
The biogeochemical cycle, is the process by which nutrients and other elements move through ecosystems and are recycled over time. There are several major biochemical cycles that play a crucial role in supporting life on Earth, including the carbon cycle, nitrogen cycle, phosphorus cycle, and water cycle.
Each of these cycles involves the movement of elements or compounds through various environmental compartments, such as the atmosphere, hydrosphere, lithosphere, and biosphere. For example, the carbon cycle involves the movement of carbon dioxide (CO2) from the atmosphere into plants through photosynthesis, where it is converted into organic matter. This organic matter is then consumed by other organisms, releasing CO2 back into the atmosphere through respiration and decomposition.
Similarly, the nitrogen cycle involves the movement of nitrogen through the atmosphere, soil, and living organisms. Nitrogen is taken up by plants in the form of nitrate or ammonium ions, which are then consumed by animals. Nitrogen is also fixed by certain bacteria in the soil, which convert it into a form that can be used by plants. Eventually, nitrogen is returned to the soil through decomposition and excretion, where it can be taken up again by plants.
The phosphorus cycle involves the movement of phosphorus through soil, water, and living organisms. Phosphorus is taken up by plants in the form of phosphate ions, which are then consumed by animals. Phosphorus is also released into the environment through weathering of rocks and minerals, and is eventually returned to the soil through decomposition and excretion.
Overall, the biochemical cycles are crucial for maintaining the balance of nutrients and elements in ecosystems, and are essential for supporting life on Earth. Any disruption to these cycles, such as through pollution or deforestation, can have significant impacts on the health and functioning of ecosystems.
Inorganic carbon cycle in depth
The inorganic carbon cycle is a process that involves the movement of carbon in its inorganic forms through various reservoirs on Earth. Inorganic carbon refers to carbon that is not part of organic matter, but instead exists as carbon dioxide (CO2), bicarbonate (HCO3-), and carbonate (CO32-) ions.
The inorganic carbon cycle is closely linked to the Earth’s atmosphere and oceans, and plays an important role in regulating the planet’s climate. Here are the main steps of the inorganic carbon cycle:
Atmospheric CO2: Carbon dioxide is a gas that is present in the Earth’s atmosphere. It is primarily released into the atmosphere through volcanic activity, respiration of organisms, and the burning of fossil fuels.
Ocean uptake: A large portion of atmospheric CO2 dissolves into the ocean, where it reacts with seawater to form bicarbonate and carbonate ions. This process, called ocean uptake, helps to regulate the concentration of CO2 in the atmosphere.
Carbonate deposition: Some of the bicarbonate and carbonate ions in the ocean react with calcium ions to form calcium carbonate (CaCO3), which can accumulate and form sedimentary rocks over time.
Carbon release: Over geologic time, carbon can be released back into the atmosphere through volcanic activity, weathering of rocks, and oceanic circulation.
The inorganic carbon cycle is important for regulating the pH of the ocean, as well as the concentration of CO2 in the atmosphere. The uptake of CO2 by the ocean helps to reduce the amount of CO2 in the atmosphere, while the deposition of carbonate minerals helps to remove carbon from the ocean. However, human activities such as the burning of fossil fuels have caused a rapid increase in atmospheric CO2 levels, which has led to changes in the climate and ocean acidification.
Inorganic carbon cycle overview:
- Timescales of instantaneous (diffusion and equilibrium) to 100’s to 1 million years
- Chemical, biological, and geological processes (instantaneous -> daily -> Ma)
- Stabalized by climate feedbacks over geologic timescales
What is important about the reservoir sizes of carbon and the transfer between them?
It gives an understanding of the big picture of how carbon (or other elements) cycle through our planet (and potentially others)
Processes to consider depend on the timescale of interest
What are the reservoirs of inorganic/oxidised carbon near earths surface?
Limestone in sedimentary rocks = 40,000,000 Gt C
HCO3- in the oceans = 37,000 Gt C
Marine carbonate sediments = 2500 Gt C
CO3 2- in the oceans = 1300 Gt C
Atmospheric CO2 = 760 Gt C
CO2 (aq) in the oceans = 740 Gt C
Inorganic medium-term carbon cycle with fluxes
The inorganic medium term carbon cycle is a process that involves the movement of carbon in its inorganic forms through various reservoirs on Earth over a period of several thousand years. Here are the main steps of the inorganic medium term carbon cycle, along with the fluxes that occur between the different reservoirs:
Atmosphere: Carbon dioxide (CO2) is present in the Earth’s atmosphere as a gas. The concentration of CO2 in the atmosphere is influenced by several processes, including the burning of fossil fuels, volcanic activity, and the respiration of organisms.
Ocean uptake: A significant amount of atmospheric CO2 is taken up by the oceans, where it reacts with seawater to form bicarbonate (HCO3-) and carbonate (CO32-) ions. This process, called ocean uptake, helps to regulate the concentration of CO2 in the atmosphere.
Sedimentary rocks: Some of the bicarbonate and carbonate ions in the ocean react with calcium ions to form calcium carbonate (CaCO3), which can accumulate and form sedimentary rocks over time. This process, called carbonate deposition, helps to remove carbon from the ocean.
Weathering: Over time, sedimentary rocks can be weathered and release CO2 back into the atmosphere. This process, called weathering, helps to regulate the concentration of CO2 in the atmosphere.
Volcanic activity: Carbon can also be released into the atmosphere through volcanic activity. Volcanic eruptions can release large amounts of CO2 into the atmosphere, contributing to changes in the Earth’s climate.
The inorganic medium term carbon cycle is important for regulating the concentration of CO2 in the atmosphere and influencing the Earth’s climate over a period of thousands of years. However, human activities such as the burning of fossil fuels have caused a rapid increase in atmospheric CO2 levels, which is leading to changes in the Earth’s climate and ocean acidification.
Inorganic long term carbon cycle
The inorganic medium term carbon cycle is a process that involves the movement of carbon in its inorganic forms through various reservoirs on Earth over a period of several thousand years. Here are the main steps of the inorganic medium term carbon cycle, along with the fluxes that occur between the different reservoirs:
Atmosphere: Carbon dioxide (CO2) is present in the Earth’s atmosphere as a gas. The concentration of CO2 in the atmosphere is influenced by several processes, including the burning of fossil fuels, volcanic activity, and the respiration of organisms.
Ocean uptake: A significant amount of atmospheric CO2 is taken up by the oceans, where it reacts with seawater to form bicarbonate (HCO3-) and carbonate (CO32-) ions. This process, called ocean uptake, helps to regulate the concentration of CO2 in the atmosphere.
Sedimentary rocks: Some of the bicarbonate and carbonate ions in the ocean react with calcium ions to form calcium carbonate (CaCO3), which can accumulate and form sedimentary rocks over time. This process, called carbonate deposition, helps to remove carbon from the ocean.
Weathering: Over time, sedimentary rocks can be weathered and release CO2 back into the atmosphere. This process, called weathering, helps to regulate the concentration of CO2 in the atmosphere.
Volcanic activity: Carbon can also be released into the atmosphere through volcanic activity. Volcanic eruptions can release large amounts of CO2 into the atmosphere, contributing to changes in the Earth’s climate.
The inorganic medium term carbon cycle is important for regulating the concentration of CO2 in the atmosphere and influencing the Earth’s climate over a period of thousands of years. However, human activities such as the burning of fossil fuels have caused a rapid increase in atmospheric CO2 levels, which is leading to changes in the Earth’s climate and ocean acidification.
Why is it useful to understand reservoir fluxes and sizes
It helps to understand roughly how long it takes a process to change a reservoir size
Eg. Total carbon in the ocean and atmosphere = 42300 Gt
Flux of CO2 removal by Si weathering = 0.03 Gt/yr
Residence time of carbon against removal by silicate weathering
= 42300 Gt / 0.03 Gt/yr - 1.5x10(6) yr
How is C02 removed from the atmosphere?
Weathering silicates remove the CO2 from the atmosphere
How does carbonic acid cause chemical weathering?
CO2 dissolves in rainwater, forms carbonic acid and dissociates
CO2 + H2O <—-> H+ + HCO3-
Rocks exposed at earths surface undergo chemical attack from this dilute acid
Chemical weathering by carbonic acid primarily affects two prominent classes of minerals - carbonates and silicates
Carbonate vs silicate weathering
Carbonate weathering and silicate weathering are two types of weathering processes that play important roles in the inorganic carbon cycle.
Carbonate weathering involves the breakdown of calcium carbonate (CaCO3) rocks, such as limestone and chalk, through exposure to rainwater and carbon dioxide (CO2) in the atmosphere. This process releases calcium ions (Ca2+) and bicarbonate ions (HCO3-) into rivers and oceans. These ions can then react with other elements to form sedimentary rocks, shells, and other marine life. Carbonate weathering helps to regulate the concentration of CO2 in the atmosphere by removing it through chemical reactions with rocks, which ultimately results in its transfer to the ocean.
Silicate weathering, on the other hand, involves the breakdown of silicate rocks, such as granite and basalt, through exposure to water and carbon dioxide in the atmosphere. This process releases silica (SiO2) and other ions such as calcium (Ca2+) and magnesium (Mg2+) into rivers and oceans. Silicate weathering plays a critical role in the long-term regulation of atmospheric CO2 levels, as it consumes CO2 through a chemical reaction between the silicate minerals and atmospheric CO2. This process also contributes to the formation of sedimentary rocks and the production of nutrients that can support plant growth.
In summary, both carbonate weathering and silicate weathering are important processes in the inorganic carbon cycle. Carbonate weathering helps to remove CO2 from the atmosphere through chemical reactions with calcium carbonate rocks, while silicate weathering helps to consume atmospheric CO2 through chemical reactions with silicate rocks.
Carbonate vs silicate weathering equations
Carbonate weathering:
CaCO3 + H2CO3 —-> Ca2+ + 2HCO3-
Silicate weathering:
CaSiO3 + 2H2CO3 —> Ca2+ + 2HCO3- + SiO2 + H2O
Much of this Ca and SiO2 re-precipitates in place in soils, but depending on relief, effective precipitation, etc. also winds up in rivers and transported to the oceans.
What is biomineralization
Biomineralisation is the process by which organisms create hard structures within their bodies, typically composed of minerals such as calcium carbonate (CaCO3) or silica (SiO2). In the oceans, biomineralisation is an important process that plays a critical role in the carbon cycle and the formation of marine ecosystems.
Marine organisms that are involved in biomineralisation include corals, mollusks, foraminifera, and coccolithophores, among others. These organisms secrete hard structures, such as shells or skeletons, that are made up of various forms of calcium carbonate or silica. The process of biomineralisation involves the precipitation of these minerals from seawater, which can be facilitated by the organism’s metabolism, pH changes, or the secretion of organic compounds.
The formation of calcium carbonate structures through biomineralisation has significant implications for the global carbon cycle. Calcium carbonate is a form of inorganic carbon, and the production of these structures by marine organisms can result in the removal of carbon dioxide (CO2) from seawater. When these structures are buried in sediment, they can contribute to the long-term storage of carbon. Additionally, the formation of these structures provides habitat for many other marine organisms, which can contribute to the formation of complex marine ecosystems.
However, ocean acidification, which is caused by the absorption of excess CO2 from the atmosphere, can negatively impact biomineralisation in the oceans. As the pH of seawater decreases, the availability of carbonate ions in seawater decreases, which can make it more difficult for marine organisms to form calcium carbonate structures. This can have significant impacts on marine ecosystems and the global carbon cycle.
What is the net effect of carbonate weathering and precipitation reactions?
Carbonate weathering and precipitation has no net effect on Carbon
What is biomineralisation?
Biomineralisation is the process by which organisms create hard structures within their bodies, typically composed of minerals such as calcium carbonate (CaCO3) or silica (SiO2). In the oceans, biomineralisation is an important process that plays a critical role in the carbon cycle and the formation of marine ecosystems.
Marine organisms that are involved in biomineralisation include corals, mollusks, foraminifera, and coccolithophores, among others. These organisms secrete hard structures, such as shells or skeletons, that are made up of various forms of calcium carbonate or silica. The process of biomineralisation involves the precipitation of these minerals from seawater, which can be facilitated by the organism’s metabolism, pH changes, or the secretion of organic compounds.
The formation of calcium carbonate structures through biomineralisation has significant implications for the global carbon cycle. Calcium carbonate is a form of inorganic carbon, and the production of these structures by marine organisms can result in the removal of carbon dioxide (CO2) from seawater. When these structures are buried in sediment, they can contribute to the long-term storage of carbon. Additionally, the formation of these structures provides habitat for many other marine organisms, which can contribute to the formation of complex marine ecosystems.
However, ocean acidification, which is caused by the absorption of excess CO2 from the atmosphere, can negatively impact biomineralisation in the oceans. As the pH of seawater decreases, the availability of carbonate ions in seawater decreases, which can make it more difficult for marine organisms to form calcium carbonate structures. This can have significant impacts on marine ecosystems and the global carbon cycle.
What is the net effect of carbonate weathering and precipitation reactions?
The net effect of carbonate weathering and precipitation reactions is the removal of carbon dioxide (CO2) from the atmosphere, which helps to regulate the Earth’s climate over long timescales.
Carbonate weathering involves the breakdown of calcium carbonate (CaCO3) rocks through exposure to rainwater and CO2 in the atmosphere. This process releases calcium ions (Ca2+) and bicarbonate ions (HCO3-) into rivers and oceans. The bicarbonate ions can react with calcium ions and other elements in seawater to form solid calcium carbonate, which can be deposited as sediment on the ocean floor. This process, known as precipitation, removes bicarbonate ions from seawater, effectively removing CO2 from the system.
The net effect of carbonate weathering and precipitation reactions is the removal of CO2 from the atmosphere, which is transferred to the ocean as dissolved inorganic carbon (DIC). This process is one of the key mechanisms by which carbon is cycled between the atmosphere, oceans, and land. Over long timescales, the removal of CO2 through carbonate weathering and precipitation reactions can help to regulate the Earth’s climate by reducing the greenhouse effect caused by excess CO2 in the atmosphere.
It is worth noting that the net effect of carbonate weathering and precipitation reactions can be influenced by a variety of factors, such as temperature, rainfall, and the type of rocks present in a given region. Additionally, changes in ocean chemistry, such as ocean acidification, can impact the rate and efficiency of these processes.