6.1 - Weathering And Soils Flashcards

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1
Q

What is the critical zone?

A

It is the shell of the earth that we live in.

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2
Q

What are the characteristics of the critical zone?

A

It is disaggregated = broken up into pieces

It is less dense than solid rock = a handful of soil is less heavy than a handful of rock (it has lost mass)

It is different colour from solid rocks = they contain different minerals and other constituents

There are plants in the top of the critical zone and more water in the critical zone than in solid rocks

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3
Q

Why are there plants in the top of the critical zone?

A

There is pore space for roots and nutrients

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4
Q

Why is there more water in the critical zone than solid rocks?

A
  • There is more pore space in the critical zone
  • The minerals are more hydrated
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5
Q

What are the 3 types of weathering?

A
  • Physical
  • Chemical
  • Biological
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6
Q

What is physical weathering?

A

Rocks and minerals break into smaller fragments with generally minor effect on composition

Physical weathering processes include
- Temperature
- Abrasion
- Plants and animals

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7
Q

How does temperature drive physical weathering?

A

Physical weathering is driven by the diurnal cycle: day (hot) and night (cool)

There is alternating expansion and contraction. The differences in expansion leads to differential stresses which causes cracks.

= breaks off rocks

  • During the day, rocks and other geological materials can heat up due to exposure to sunlight, which can cause them to expand. At night, these materials can cool down and contract. Over time, repeated cycles of expansion and contraction can cause the materials to break down and crack, which can lead to physical weathering.
  • Winds are often stronger during the daytime when temperature differences between land and sea are greater. These strong winds can cause rocks and other materials to rub against each other, which can lead to abrasion and further physical weathering.
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8
Q

What is temperature-induced exfoliation?

A

It is the peeling away of rock layers because of stresses induced by outer layers being warmer or colder than inner portions.

  • When rocks are heated by the sun during the day, they can expand, causing stress on the surface of the rock. At night, when temperatures drop rapidly, the outer layers of the rock can contract and cool down faster than the interior of the rock. This creates tension within the rock, and if this tension becomes too great, the outer layers can split off, resulting in exfoliation.
  • Canada experiences extreme temp differences from day to night
  • Exfoliation is influenced by underlying mineralogy
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9
Q

What is frost wedging?

A

It is the breaking of rock when water expands as ice inside pore spaces

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10
Q

How does abrasion drive physical weathering?

A

It occurs when rocks and other geological materials are worn down by frictional forces. This process is driven by the movement of water, wind, or ice, which can transport sediment and other materials across the surface of rocks, leading to erosion and abrasion.

Water:
- Freeze/thaw
- Flow can dislodge bits of rock
- Debris in water (rocks, sediments) abrades other rocks it flows over. This causes rounding of rocks and grains in rivers/shores

Wind:
- The debris in wind (eg. Slit,clay and sand) abrades rocks

Ice
- Freeze/thaw
- Debris in ice (rocks and sediments) abrades rocls
- Ice also transports lots of ground up rock material

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11
Q

How can plants and animals drive physical weathering?

A
  • Plant roots enhance physical disintegration by entering cracks in rocks and prying them apart
  • Burrowing organisms have a very minor effect (although can significantly affect chemical weathering)

Neither of these physical processes are globally significant compared to the actions of water, ice, wind and temperature

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12
Q

What happens when physical weathering breaks up a rock?

A

The rock is broken up into smaller pieces without changing the chemical make p of the rock.

  • The larger the surface area of the rock, it has increased exposure to chemical weathering
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13
Q

Why do chemical reactions alter rocks and minerals at earth surface (near-surface) conditions?

A

Because most rock-forming minerals (primary minerals) are not thermodynamically stable at earths surface temperature and pressure

  • Rock-forming minerals at Earth’s surface are not thermodynamically stable because they have formed under conditions of high temperature and pressure, which are typically found deep within the Earth’s interior. When these minerals are exposed to the lower temperature and pressure conditions found at the Earth’s surface, they can become unstable and undergo chemical reactions or physical changes that lead to their breakdown and alteration.
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14
Q

What factors could affect chemical weathering?

A

Temperature = chemical reactions are usually faster at higher temps. There is often more liquid water and biology available at higher temps

Water and water flow = carries reactants to the rock and carries products away

Reactants = acids and/or oxygen

Products = if concentration of dissolved products are too high the reaction will slow and stop

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15
Q

What are net results of chemical weathering

A

Convert primary minerals (eg. Feldspars) to secondary minerals (eg. Clays)

Deliver nutrients (eg. P) from rocks to biosphere in soluble forms

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16
Q

What is the reverse Bowen’s reaction series?

A

It is useful as a rough guide to the susceptibility of minerals to chemical weathering.

  • In the original Bowen’s reaction series, minerals crystallize out of a magma as it cools, while in the reverse sequence, minerals melt as the rock is heated.
  • The reverse Bowen’s reaction series begins with the melting of the most stable mineral, quartz. As the temperature continues to increase, other minerals in the rock will begin to melt, in the reverse order of their stability. For example, feldspars will melt before micas, and micas will melt before amphiboles. (quartz, feldspars, micas, amphiboles)
  • As minerals undergo weathering, they can transform into new minerals that are more stable under the current environmental conditions. The reverse Bowen’s reaction series helps us understand which minerals are more likely to undergo weathering and how they might change during this process.
  • For example, minerals that are less stable at Earth’s surface, such as olivine and pyroxene, may be more susceptible to chemical weathering than more stable minerals like quartz and feldspar
17
Q

What are the 3 types of chemical weathering reactions?

A

1) Dissolution

2) Direct transformation of minerals

3) Precipitation of secondary minerals

18
Q

What is dissolution?

A

Dissolution usually occurs by acid attack: H+ (proton-promoted dissolution)

H+ ions come from various sources
- Water: H20 -> H+ + OH-

Other acids: carbonic acid (H2CO3), nitric acid (HN03), Sulfuric acid (H2S04), organic acids

H+ ions dissolve minerals primarily via hydrolysis (H+ replaces cation in mineral, breaking it apart)

19
Q

What is an example of dissolution?

A

Hydrolysis of K-feldspar

KAISi3O8 + H20 —> HAISi3O8 + K+ + OH-

2 HAISi3O8 + 11 H2O —> Al2O3 + 6 H4SiO4

Soluble product (K+) can flow away from the reaction site (mass loss)

(K-feldspar reacts with water, the K+ , can then flow away from the reaction site)

20
Q

What is one of the primary agents of chemical weathering on earth?

A

Carbonic acid (H2CO3) is one of the primary agents of chemical weathering on earth. It occurs in rainwater and from microbial respiration.

Carbon gas dissolves = CO2 + H2O <—> H2CO3

Carbon acid causes dissolution of calcite = H2CO3 + CaCO3 —> Ca2+ + 2 HCO3-

This is essentially a hydrolysis reaction:
H2CO3 —> H+ HCO3-
H+ CaCO3 —> Ca2+ + HCO3-

21
Q

What is the importance of calcite?

A

It is important for the stability of the earth’s climate (carbon cycle) by storing carbon over geological timescales.

  • Calcite is a form of calcium carbonate, and it is a major component of sedimentary rocks, such as limestone and chalk.
  • Calcite is formed when carbon dioxide from the atmosphere dissolves in water and reacts with calcium ions, producing calcium carbonate.
  • Calcite also forms the shells of marine organisms, such as corals and plankton, which remove carbon dioxide from the ocean and sequester it in their shells.

It can also dissolve silicates

22
Q

What are the 2 types of dissolution?

A

1) Congruent dissolution = whole mineral dissolves

2) Incongruent dissolution = some elements are preferentially dissolved

23
Q

What are the 3 direct transformations of minerals?

A

1) Hydration

2) Oxidation / reduction

3) Cation exchange

24
Q

What is hydration?

A

It is the binding of water molecules to a mineral

Hydration produces many common secondary minerals eg. Hydroxides of Fe and Al

5 Fe2O3 + 9 H2O —> Fe10O15 . 9H20

25
Q

What is oxidation-reduction

A
  • AKA redox reactions

Example : Fe(II) —> Fe (III) in biotite

  • Fe (III) has different charge and therefore “ionic radius”
    (Rocks containing iron, fe(II) minerals can transform to Fe(III)

There is destabilisation or adjustments in crystal structure and loss of other elements to maintain charge balance.

Most common = Fe, Mn, S

26
Q

What do most oxidation reactions involve?

A

Oxidation reactions involve both dissolution and precipitation

FeSiO4 (olivine) + 8H —> H4SiO42 (aq) + Fe2+ (aq) + 2H2O

4Fe2+ (aq) + O2 + 10H2O —> 4Fe3+ (OH)3 (s) + 8H+
Aqueous Fe (II). Fe (III) - hydroxide “ferrihydrite”

27
Q

What minerals make soil red/orange?

A

Fe (III) - (hydr)oxide minerals

Eg. Ferrihydrite, goethite, hematite

28
Q

What minerals make soil appear black?

A

Mn (III,IV) - (hydr)oxide minerals appear as black accumulations in soils

Mn = Manganese

29
Q

What is cation exchange?

A

Common cations are K+, Na+, Ca2+, Mg2+

Cation exchange is common with clays and other phyllosilicates

Usually it is inter layer cations that swap. This results in different mineral composition and can affect crystal structure.

(Cation exchange is also used to refer to adsorption-desorption of ions on mineral surfaces)

30
Q

What are the 2 different precipitations of secondary minerals?

A

1) Oxides and hydroxides = goethite, ferrihydrite, gibbsite…

2) Clays = kaolinite, smectite, montmorillonite…

  • along with other soluble products
31
Q

What does rock and mineral weathering produce?

A

Rock and mineral weathering both produce soluble and insoluble products

Soluble = Fe (II)

Insoluble = Fe (III)

32
Q

What can happen to soluble products?

A
  • Adsorption (eg. Cation exchange)
  • Leaching and translocation
  • Leaching and removal (eg. By erosion or uptake by plants)
33
Q

What can happen to insoluble products?

A
  • Translocate (Eg. To another depth in the soil profile)
  • Precipitate (eg. Remain in the same place)
34
Q

How can fungi cause physical and chemical weathering?

A

Fungi excrete humid acids which cause in situ chemical weathering, releasing nutrients (primarily P).

Fungi and plant root symbiosis means that both parties benefit from each other.

35
Q

What is an example of fungi and plant root symbiosis?

A

Pinus sylvestris (Scot’s pine) seedlings with paxillus involutus (fungi)

Lichens

  • In a lichen, a fungus forms a symbiotic association with either a green algae or a cyanobacterium, which provides the lichen with the ability to photosynthesize and produce carbohydrates. The fungus, in turn, provides the lichen with protection, structural support, and access to nutrients.
36
Q

What do lichens do?

A

Lichens enhance both physical and chemical weathering.

Physical = They penetrate cracks, expand and contract
Chemical = They secrete organic acids (oxalic acid mainly)

1) lichens grow on top of rock
2) lichens penetrate weaknesses in rock and expand and contract
3) lichens continue to grow and take over rock
4) the organism overtakes rock and continues to break up the rock = this increased SA leads to increased weathering

Solutes released by chemical weathering can precipitate (sometime weird) secondary minerals can also occur

37
Q

How is a critical zone created?

A
  1. Break down rock via physical and/or chemical weathering (likely with biological enhancement)
  2. Two options
  • In situ critical zone : CZ evolves (continues weathering, organisms colonise, soil layer forms, erosion happens…)
  • Deposited critical zone : weathered products are transported and deposited, before local CZ evolves
38
Q

How is weathering a unifying process across the earth sciences?

A

Weathering is on a timescale and spatial scale

Timescale= weathering from over seconds to billions of years
Spatial scale= weathering over nm to planetary scale