6.2.1 Amines Flashcards

1
Q

Why do amines behave as bases

A

Lone pair of electrons on the nitrogen can accept a proton

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2
Q

Amine plus acid

A

Ammonium salt forms

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3
Q

How to prepare a primary amine

A

Haloalkane plus excess ammonia in presence of ethanol forms ammonium salt
Add sodium hydroxide to ammonium salt to from amine and sodium salt and water

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4
Q

How to prepare secondary and tertiary amines

A

Secondary amine formed from further substitution from reaction for primary amine
Tertiary amine formed from further substitution from reaction for secondary amine

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5
Q

How to prepare aromatic amines

A

Heat nitrobenzene under reflux with tin and HCl to form an ammonium salt (reduction)
React with excess NaOH to form phenylamine

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