6.1 Shapes of molecules and ions Flashcards
what is the electron-repulsion theory?
electrons have a negative charge so electron pairs repel each other
the shapes of molecules are determined by the level of repulsion from the electron pairs
electron pairs repel each other as far apart as possible to minimise repulsion
in a 3d diagram what is the wedge shape?
plane coming out of the paper
in a 3d diagram what is the dotted wedge?
plane going into the paper
what are the two types of electron pairs?
bond pairs
lone pairs
what is the interaction between a bond pair and a lone pair?
lone pairs repel more strongly than bond pairs
what effect does a lone pair have on the bond pairs?
by repelling the bond pairs, the angle between bond pairs decreases
by how much does a lone pair decrease the bond angle?
2.5 degrees
4 bond
0 lone
tetrahedral
109.5
3 bond
1 lone
pyramidal
107
2 bond
2 lone
non-linear
104.5
2 bond
0 lone
linear
180
3 bond
0 lone
trigonal planar
120
6 bond
0 lone
octahedral
90