6 Rate and exchange Flashcards
Exothermic Reaction
a reaction which transfers energy to it’s surroundings usually in the form of heat
endothermic reaction
a reaction which absorbs energy from its surroundings usually in the form of heat
rate of reaction (g/s)(cm³/s) =
amount of reactant used or amount of product formed (cm³/g) /
time (s)
rate of reaction def
how fast reactants are changed into products
what is the activation energy
minimum amount of energy that particles need to for bonds to break and particles to react
different for each reaction
what is collision theory
Particles must react with enough energy in order ot react
factors affecting rates of reaction
- temperature
- concentration of a solution (liquid)
- pressure in a surface area (gas)
- pressence of a catalyst
how does temperature affect rate of reaction
- when temp increases particles gain more kinetic energy so they move faster
- If they are moving faster there will be more frequent collsions increasing frequencey of succesful collsions with the activation energy
- therfore a higher rate of reaction
how does concentration and pressure affect rate of reaction
- if a solution is more concentrated there are more particles colliding in the same volume as solvent
- if pressure of a gas is increased there are same amount of particles in a smaller space
- this makes collisions more frequent therefore the frequncey of succesful collisons increases which are meeting the activation energy therefore a higher rate of reaction
How does surface area affect the rate of reaction
- higher surface area increases surface area to volume ratio therefore there is more surface area for particles to collide with
- for the same volume of solid, particles around will have more area to collide with
- therefore number of collisions high therefore frequency of successful collisions which reached their activation energy is higher
- therefore higher rate of reaction
how does the use of a catalyst affect the rate of reaction
- a catalyst lowers activation energy by providing an alternative reaction pathway
- so particles need a lower energy to reach their activation energy making it easier to reach this activation energy
- therefore more frequent successful collisions therefore higher rate of reaction
- catalysts dont get used up in reactions
reaction pathway diagram/graph exothermic
- energy on y axis, progress of reaction on x axis
- reactants start high product is low
- activation energy from reactant line to top - arrow up
- energy change from reactant line to product line - arrow down
- if drawing reaction path with catalyst make the curve of activation energy smaller than normal
- reaction pathways!
reaction pathway diagram/graph endothermic
- energy on y axis, progress of reaction on x axis
- reactants start low product is high
- activation energy from reactant line to top - arrow up
- energy change from reactant line to product line - arrow up
- if drawing reaction path with catalyst make the curve of activation energy smaller than normal
- reaction pathways!
what happens as reactants react
their concentration falls so the forward reaction will slow down
what happens as more product is formed
their concentration rises so the backwards reaction will speed up