1 Atomic structure and the periodic table Flashcards
how to do paper chromotography
- Use a ruler to draw a horizontal pencil line 2 cm from the bottom short edge of the chromatography paper- origin line
- add a spot of ink to the line and place the sheet in a beaker of solvent eg. water
- add the piece of paper into the water with only the bottom submerdeged eg. 1cm
- clip the top to a wooden spill resting on the top of the beaker
- put a lid on top to stop the solvent evaporating
- the solvent seeps up the paper carrying the ink with it
- each dye in the ink will move up the paper at different rate forming a spot
- if any ink is insoluable it will stay on the baseline
- when the solvent has nearly reached the top of the paper take it out and dry it
- the end result is a chromotogram
how to seperate insoluble solids from liquids
- filytration
- filter ppaer folded into a cone shape - solide is let in the filter paper
how to seperate soluble solids from solution
- evaporation
- crystallisation
how to seperate a soluble solid from a solution using evaporation
- pour solution into evaporation dish
- slowly heat the solution
- solvent will evaporate
- solution gets more concentrated
- crystals form
- heat until all left is dry crystals
how to seperate a soluble solid from a solution using crystallisation
- pour solution into evporating dish
- gently heat
- some solvent will evaporate and solution gets more concentrated
- once some solvent evaporated or when crystals start to form, remove dish from hea and leave to cool
- salt shoudl form crystals as it becomes insoluble in the cold, highly concentrated solution
- filter the crystals out of solution
- leave them in warm place to dry
- use a dryign oven or desiccator
how to do distillation
- solution is heated, part of solution that has lowest boiling point evaporates first
- vapur is colled, condensed and collected
- in the tube carrying the condensed water a condensor goes around it - water goes in from the bottm and water out from the top
- cna be used to seperate solutions of very dfferent boiling temps
explain the alpha particle experiment and what it achieved
- fired positive alpha particles at a thin sheet of gold
- from plum pudding model, expecting for paeticles to pass straigth throigh or besligthly deflected at most - believed postive charge of each atom was thougth to be veyr spread out
- while most particles did go straight through some delfexted mro ethan expected and backwards - plum pudding model can’t be right
- led to discovery of nucleus at the centre, where nost mass is concentrated, a ‘cloud’ of negative charge sourrounds, so most of the psace is empty
- when the alpha particles cam enear the nucleus they were dlefected - positive and positive
order of models of the atom
- 19th centruy, John Dalton, described atoms as solid spheres
- 1897 JJ Thompson, discovered existence of electrons, plum pudding model, ball of positive chare with negative elctrons embeded in it
- 1909 Ernest Rutherfod nuclear model, most of the atom empty space, nucleus in the centre with concentrated mass, positive, ‘cloud’ of electrons surrounded the nucleus
- Bohr , proposed electrons orbit in shells around the nucleus
- James Chadwick dicovered neutrons
how did Mendeleev order elements in the periodic table
- order of atomic mass
- wouls swich order if porperties meant it should be changes
- previously it was ordered by relatiev atomic mass
why did mendeleev switch Te and I
- Iodine has smaller relative atomic mass but placed after terilium as it has similiar properties as group 7
why did Mendeleev leave gaps in his periodic table
- to make sure elements wiht similiar properties staued in the same groups
- the se gaos indicated existence of undisovered elements, allowed Mendeleev to predict their properties
- made really good predictions on ekasilicon - germanium
- discovery of isotopes proves mendeleev was right to only pace by atomic mass
properties of metals
- form posite ions when react
- strong, are malleable
- good conductors of heat and electricty
- have high melting and boiling point
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properties of non metals
- brittle
- aren’t always solids at room temperature
- don’t generally conduct electricty
- have lowe density
properties of transition metals
- same as metals
- cna have mroe than one ion eg. Cu+ Cu2+
- often coloured, so compunds containing theses tned to be colourful
- make good catalysts
group 1 elements properties
- one electron in outer shell so very reactive
- soft
- low density
trend as you go down group 1
- increasing reactivity- outer electron is more easily lost, attraction between nucleus and elctron decreases, electron further away form nucleus
- lower meltign and boilign points - outer electron easily lost…
- higher relative atomci mass
group 1 reacting with differenet substances
- form 1+ ions
- form ionic compounds
- usually form white compounds
what can you observe when a group 1 element reacts with water
- react vigorously to produce hydorgen gas and metal hydorxides - salts dissolve in water to produce alkaine solutions - OH-
- more reactive an alkali metal is the more violent the reaction
- amount of energy given out by the reaction increases down the group
what can you observe when a group 1 element reacts with chlorine
- react vigiursly when heated in chlorine gas to form white metal chloride salts
- as you go down the group, reactivity increases so reatcion gets more vigorous
what can you observe when a group 1 element reacts with oxygen
- form a metal oxide
- different types of oxide forms depending on the metal
group 7 (halogens) properties
- less reactive as you go down the group
- higehr melting and boiling points as you go down
- higher relative atomic mass as you go
- more reactive halogens displace less reactive ones
noble gasses properties
- all inert
- all coloured gasses
- boilign points increase as move down the group - due to increae in number of electrons in each atom so greater intermolecular forces