5 Energy changes Flashcards

1
Q

what is an exothermic reaction

A
  • transfers energy to its surroundings - rise in temp of surroundings
  • eg. combustion
How well did you know this?
1
Not at all
2
3
4
5
Perfectly
2
Q

what is an endothermic reaction

A
  • takes in energy from its surroundings
  • fall in temp of surrounding
How well did you know this?
1
Not at all
2
3
4
5
Perfectly
3
Q

practical measuring energy transfer

A
How well did you know this?
1
Not at all
2
3
4
5
Perfectly
4
Q

exothermic reaction profile

A
  • energy on x
  • progress of reaction on y
  • reactants at the top
  • products on the bottom
  • activation energy from reactants to peak
  • energy released from reactants to products
How well did you know this?
1
Not at all
2
3
4
5
Perfectly
5
Q

endothermic reaction profile

A
  • energy on x
  • progress on y
  • reactants in bottom
  • products at top
  • activation energy from reactants to peak
  • energy change from reactants to absorbed
How well did you know this?
1
Not at all
2
3
4
5
Perfectly
6
Q

what is activation energy

A
  • minimum amount of energy that reactants need to collide with each other and react
  • greater the activation energy the more energy needed to start the reaction
  • catalysts provide an alternative reaction pathway with a lower activation energy
How well did you know this?
1
Not at all
2
3
4
5
Perfectly
7
Q

in which reaction do bonds break

A
  • endothermic
  • energy must be supplied to break existing bonds
How well did you know this?
1
Not at all
2
3
4
5
Perfectly
8
Q

in which reaction do bonds form

A
  • exothermic
  • energy released when new bonds are formed
How well did you know this?
1
Not at all
2
3
4
5
Perfectly
9
Q

how to calculate overall energy change

A

sum of energy released when breaking bonds - energy released when forming

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
10
Q

how to produce an electrochemical cell

A
  • in a beaker put an electrolyte eg. NaCl
  • must have 2 electrodes which are able to conduct electricity
  • both are connected with wire
How well did you know this?
1
Not at all
2
3
4
5
Perfectly
11
Q

how does a cell work

A
  • chemical reactions between the electrodes set a charge difference between the electrodes
  • elctrodes are connected with wire which alows the charge to flow and electricity is produced
  • voltmeter can be connected to measure the voltage of the cell
How well did you know this?
1
Not at all
2
3
4
5
Perfectly
12
Q

what does the voltage fo a cell depend on

A
  • type of electrode used - different metals react differently
  • the bigger the difference in reactivity the bigger the voltage
  • the electrolyte used - different ions in solution will react differently with the metal
  • wether there are multiple cells connected - battery, in battery voltage will be bigger overall
How well did you know this?
1
Not at all
2
3
4
5
Perfectly
13
Q

how do non-rechargable batteries work

A
  • chemical reactions that happens at thelectrodes are irreversible
  • overtime the reactant particle -ions in electrolyte, metal ions in electrode get used up and turn into products of reaction
  • one a reactant in used up a reaction can’t happen so no electricity is produced
  • products can’t be turned back into reactants so cell can’t be reacharge
  • however in rechargeable reaction can be reversed by connecting it to an external electric current
How well did you know this?
1
Not at all
2
3
4
5
Perfectly
14
Q

in fuel cells which one is the cathode and anode

A
  • cathode - positive
  • anode - negative
How well did you know this?
1
Not at all
2
3
4
5
Perfectly
15
Q

how do fuel cells work

A
  • electrolyte is often a solution of potassium hydroxide
  • eletrodes are porous carbon with a catalyst
  • hydrogen goes into the anode compartment and oxygen goes into the cathode compartment
  • at the -ve elctrode anode hydrogen looses electrons to produce H+ ions -oxidation
  • H+ ions move to the cathode +ve
  • at the +ve elctrode, oxygen gains electrons form he cathode and react with H+ ions to make water - reduction
  • electrons flow though an external circuit from the anode to the cathode - produces electric current
  • overall reation is hydrogen plus oxygen
How well did you know this?
1
Not at all
2
3
4
5
Perfectly
16
Q

advantages for fuel cells

A
  • don’t produce as many pollutants as other fuels - no greenhouse gasses, nitrogen oxides sulfur dioxides or carbon monxide
  • electric vehicles don’t produce many pollutants either - their batteries are more poluting to dispose of than fuel cells because made for toxic compounds
  • batteries are rechargable - limit to how many times, batteries more expensive
17
Q

disadvantages of fuel cells

A
  • hydrogen is a gas, so takes up a lot of space to tore than a rechargable battery
  • hydrogen is explosive when mixed with air so it’s hard to store safely
  • often made either from hydrocarbons or by electrolysis for water which uses electricity which is usually generated by burning fossil fuels