6 - Acids and Bases Flashcards

1
Q

Arrhenius acid=

Arrhenius base=

Bronsted and Lowry acid=

Bronsted and Lowry base=

Lewis acid=

Lewis base=

pH =

A

Arrhenius acid= is anything that produces hydrogen ions in aqueous solution.

Arrhenius base= anything that produces hydroxide ions in aqueous solution.

Bronsted and Lowry acid= anything that donates a proton.

Bronsted and Lowry base= anything that accepts a proton.

Lewis acid= anything that accepts a pair of electrons.

Lewis base= anything that donates a pair of electrons.

pH = -log[H+]

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2
Q

Amphoteric=

*Acid taste _______, Bases taste ________

*Bases are _________ when wet

*Many reactions in living cells involve the transfer of a _______. The rate of such reactions depends upon the concentration of ____________

A

Amphoteric= substances that act as either an acid or base depending on their environment.

*Acid taste sour or tart, Bases taste bitter

*Bases are slippery when wet

*Many reactions in living cells involve the transfer of a proton. The rate of such reactions depends upon the concentration of H+ ions or the pH.

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3
Q

Polyprotic acids=

Diprotic acid=

*Assume that strong acids or bases completely _____ in water.

*in a series of oxyacids, more _______ means a stronger acids!

A

Polyprotic acids= acids that can donate more than one proton.

Diprotic acid= an acid that can donate two protons.

*Assume that strong acids or bases completely dissociate in water.

*in a series of oxyacids, more oxygens means a stronger acids!

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4
Q

Autoionization of water=
H2O + H2O –>

Kw =

A

Autoionization of water= pure water reacts with itself to form hydronium and hydroxide ions as follows:
H2O + H2O –> H3O+ + OH-

Kw = [H+][OH-]

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5
Q

Acid dissociation constant Ka=
Ka = (equation)

Kb=
Kb = (equation)

*a pKa less than _____ or a Ka greater than ____ indicates a strong base.

A

Acid dissociation constant Ka= an acid will have its own equilibrium constant in water.
Ka = [H+][A-]
[HA]

Kb= the equilibrium constant for the reaction of the conjugate base with water.
Kb = [OH-][HA]
[A-]

*a pKa less than zero or a Ka greater than 1 indicates a strong base.

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6
Q

Salts=

*When considering salts, remember all ____, except those of the ______act as weak lewis acids in aqueous solutions.

A

Salts= are ionic compounds that dissociate in water. They dissociate creating acidic or basic conditions.

*When considering salts, remember all cations, except those of the alkali metals and the heavier alkaline earth metals (Ca, Sr, and Ba) act as weak lewis acids in aqueous solutions.

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7
Q

Titration=

Titrant=

A

Titration= a drop by drop mixing of an acid and a base.

Titrant= titrations are performed in order to find the concentration of some unknown by comparing it with the concentration of the titrant.

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8
Q

Half equivalence point=

Buffered=

pH =

A

Half equivalence point= is the point where exactly one half of the acid has been neutralized by the base.

Buffered= the spot where we could add the largest amount of base or acid with the least amount of change in pH.

pH = pKa + log [A-]
[HA]

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9
Q

Indicator=

Buffer=

A

Indicator= is a chemical that can be used to find the eq. point; and it has two points of color change which give the range of an indicator. Endpoint is where the indicator changes color.

Buffer= is weak acid and its conjugate base. And pH = pKa

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