5.1 VSEPR model Flashcards

0
Q

what does VSEPR stand for?

A

valance shell e- pair repulsion

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1
Q

what is the name given to the 3D arrangement of atoms in a molecule

A

molecular structure

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2
Q

when is VSEPR best utilized?

A

to predict the 3D geometry of molecules formed from nonmetals

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3
Q

the main idea of VSEPR

A

is to minimize e- pair repulsions

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4
Q

what is the degree of the angles in a tetrahedral structure?

A

109.5

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5
Q

when should prs of e-‘s be arranged tetrahedrally?

A

when there are 4 prs of e-‘s around an atom

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6
Q

what is the first step in a VSEPR model?

A

draw the lewis structure

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7
Q

what is the 2nd step to a VSEPR model?

A

count the e- pairs and arrange them in a way that minimizes repulsion (put them as far apart as possible)

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8
Q

what is the 3rd step in a VSEPR model?

A

determine the positions of the atoms from the WAY the e- pairs are shared

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9
Q

when does a molecular structure VSEPR model get named?

A

after the positions of the atoms is determined in step 3

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10
Q

which requires more room? bonding pairs or lone pairs?

A

lone pairs

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11
Q

because lone pairs require more room than bonding pairs, what happens to the angles between the bonding pairs?

A

they get compressed to give the lone pairs more space on the orbitals of the atom they belong to.

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12
Q

what is the arrangement of 2 e- prs around an atom that yields minimum repulsion

A

linear

180 degrees

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13
Q

what is the arrangement of 3 e- prs around an atom that yields minimum repulsion

A

Trigonal planar

120 degrees

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14
Q

the tetrahedral arrangement of e- pairs is used for how many e- pairs?

A

4

109.5 degrees

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15
Q

the trigonal bipyramidal arrangement of e- pairs is used for how many e- pairs?

A

5

120/90 degrees

16
Q

the octahedral arrangement of e- pairs is used for how many e- pairs?

A

6

90 degrees

17
Q

what is the molecular structure of a molecule with 4 bonding e- pairs?

A

tetrahedral

18
Q

what is the molecular structure of a molecule with 3 bonding e- pairs and 1 lone pr?

A

trigonal pyramid

19
Q

what is the molecular structure of a molecule with 2 bonding e- pairs and 2 lone e- prs?

A

V-shaped (or bent)

20
Q

what is the molecular structure of a molecule with 5 bonding e- pairs?

A

trigonal bipyramid

21
Q

the see-saw structure is seen in molecules with how many bonding and lone pairs?

A

4 bonding

1 lone pair

22
Q

the T-shaped structure is seen in molecules with how many bonding and lone e- prs?

A

3 bonding

2 lone prs

23
Q

what are the possible molecular structures for molecules with 4 e pairs?

A

tetrahedral
trigonal pyramid
v-shaped (or bent)

24
Q

what are the possible molecular structures for molecules with 5 e- pairs?

A

trigonal bipyramidal
see-saw
t-shaped
linear

25
Q

in VSEPR model, a double bond is counted as

A

on effective pair

26
Q

when a molecule exhibits resonance, which resonance structure should be used to predict the molecular structure in the VSEPR model?

A

any of them

27
Q

what degree angle provides lone pairs with enough space so that distortions do not occur?

A

120

28
Q

the mixing of the native atomic orbitals to create special orbitals for bonding

A

hybridization

29
Q

sp3 hybridization or saying an atom is sp3 hybridized means

A

its orbitals formed from 1 2s and 3 2p orbitals (s1p3)

30
Q

whenever a set of equivilent tetrahedral atomic orbitals is required by an atom in a molecule, the model assumes that the atom adopts a set of ___ orbitals; the atom is ____ ________

A

sp3

sp3 hybridized