4.10-11-12 lewis structures Flashcards
what is the duet rule? and which elements follow it?
2 e-‘s in the 1s valance shell
H and He
which e-‘s are included in lewis structures?
only val e-‘s
why does He not form bonds?
its valance shell is full
what is the octet rule?
atoms need to be surrounded by 8 e-‘s
what is the first step in writing a lewis structure?
sum the val e-‘s of all the atoms
what is the 2nd step in writing a lewis structure?
use a pair of e-‘s to form bonds between each pair of atoms (one pair of e-‘s for each pair of atoms)
what is the 3rd step in writing a lewis structure?
arrange the remaining e-‘s to satisfy the duet or octet rules
which elements can exceed the octet rule?
those in pd 3 and beyond (they have access to the D orbitals)
which elements often have fewer that 8 e-‘s around them in their compounds?
B
Be
if it is necessary to exceed the octet rule, where should the extra e-‘s get placed?
the central atom
when is resonance used?
when more than one valid lewis structure can be given for a particular molecule
what is the actual structure of a molecule with more than one valid structure?
an average of the resonance structures
describe formal charge of an atom
the difference between the # of e-‘s an atom has in its free state and the # of e-‘s assigned to it in the compound (actual - assigned)
what type of formal charges do atoms in molecules try to acheive
closest to 0
where are negative formal charges expected to reside?
the most electronegative atom