5 - formulae equations and amounts Flashcards
empirical formula
shows the smallest whole-number ratio of atoms of each element in a compound
molecular formula
shows the actual number of atoms of each element in a molecule
molar mass
the mass per mole of a substance. it has the symbol M and the units g mol-1
mole
the amount of substance that contains the same number of particles as the number of carbon atoms in exactly 12g of the carbon-12 isotope
avogadro constant
the number of atoms of 12C in exactly 12g of carbon-12
coefficients
the numbers written in front of the species when balancing an equation
spectator ions
the ions in an ionic compound that do not take part in a reaction
hydrates
compounds containing water of crystallisation, represented by formulae such as CuSO4.5H2O
avogadros law
states that equal volumes of gases under the same conditions of temperature and pressure contain the same numbers of molecules
molar volume
the volume occupied by 1 mol of any gas
solute
a substance that is dissolved
solvent
a substance that dissolves a solute
solution
a solute dissolved in a solution
mass concentration
of a solution is the mass (in g) of the solute divided by the volume of the solution
molar concentration
a solution is the amount (in mol) of the solute divided by the volume of the solution
standard solution
a solution whose concentration is accurately known
primary standards
substances used to make a standard solution by weighing
equivalence point
the point at which there are exactly the right amounts of substances to complete the reaction
end point
the point at which the indicator just changes colour. ideally, the end point should coincide with the equivalence point
meniscus
the curving of the upper surface in a liquid in a container. the lowest (horizontal) part of the meniscus should be read
titre
the volume added from the burette during a titration
concordant titres
those that are close together (usually within 0.2 cm3 of each other)
error
the difference between an experimental value and the accepted or correct value
accuracy
a measure of how close values are to the accepted or correct value
precision
a measure of how close values are to each other
random errors
errors caused by unpredictable variations in conditions
systematic errors
errors that are constant or predictable, usually because of the apparatus used
measurement uncertainty
the potential error involved when using a piece of apparatus to make a measurement
percentage uncertainty
the actual measurement uncertainty multiplied by 100 and divided by the value recorded
theoretical yield
the maximum possible mass of a product, assuming complete reaction and no losses
actual yield
the actual mass obtained
percentage yield
is 100x the actual yield divided by the theoretical yield
atom economy
the molar mass of the desired product divided by the sum of the molar masses of the products, expressed as a percentage
displacement reaction
a reaction in which one element replaces another element in a compound
precipitation reaction
where an insoluble solid is one of the products