5. Energetics Flashcards
Temperature
A measure of the average kinetic energy of particles
Exothermic reaction
Heat energy is transferred from a system to the surroundings (surroundings get hotter)
Endothermic reaction
A system takes in heat energy from the surroundings (the surroundings get cooler)
Standard enthalpy change of combustion
The enthalpy change when one mole of a substance is completely burnt in oxygen under standard conditions
Enthalpy change of solution
The amount of heat energy given out/taken in when 1 mole of solute dissolves in excess solvent
Enthalpy change of formation
The enthalpy change when one mole of the substance is formed from its elements in their standard states under standard conditions
Hess’s Law
The enthalpy change accompanying a chemical reaction is independent of the pathway between the initial and final states
Average bond enthalpy
The energy required to break one mole of covalent bonds in a gaseous molecule under standard conditions (the average amount of energy to break a particular bond in a range of similar molecules)
Entropy
A measure of how the available energy is distributed among the particles
Spontaneous reaction
Reaction that occurs without any outside influence