4b (Crude oil) Flashcards
What is oil?
Oil is a mixture of hydrocarbons
Process of fractional distillation to separate crude oil
- Crude oil is separated by fractional distillation
- Crude oil is heated and the oil evaporates
- The gas goes into the fractional distillation tower. As the gas rises the temperature falls
- Fractions with higher boiling points condense and are collected nearer the bottom of the tower
Name and uses of fractions (in order):
-Refinery gases (Bottled gas)
- Gasoline (gasoline for cars)
- Kerosene (Jet Fuel and Paraffin)
- Diesel (fuels)
- Fuel Oil (Fuel for heating and ships)
- Residue / bitumen (for roads and roofing)
What is fuel?
A fuel is a substance that, when burned, releases heat energy (exothermic reaction)
Complete combustion products
Carbon dioxide and water
Incomplete combustion products
Carbon monoxide and water
When does complete o incomplete combustion occur?
- Complete combustion occurs when there is enough oxygen available
- Incomplete combustion occurs when there is not enough oxyygen
Why is carbon monoxide poisonous?
- Carbon monoxide is produced from incomplete combustion
- It is poisonous becuase it reduces the capacity of the blood to carry oxygen
Why do high temperatures are reached in car engines?
- When fuels are burned in vehicle engines, high temperatures are reached.
- At these high temperatures nitrogen and oxygen from the air react to produce nitrogen oxides
- In the atmosphere these nitrogen oxides can combine with water to produce nitric acid (HNO3)
How hydrocarbon fuels results in the formation of sulfur dioxide?
- Fossil fuels such as coal, gas and oil are derived from crude oil.
- These fuels are hydrocarbons, but also include impurities such as sulfur.
- When the fuels are burned, sulfur dioxide is produced which can escape into the atmosphere
How is acid rain formed?
- Sulphur dioxide in the atmosphere reacts with water (and oxygen(which prouces a stronger acid)) to produce sulphuric acid
- Nitrogen oxide reacts with water and causes nitric acid
How long-chain alkanes are converted to alkenes and shorter-chain alkanes
by catalytic cracking
- Cracking involves the thermal decomposition of long-chain alkanes into shorter-chain alkanes and alkenes
- Temperature: 600oC
- Catalyst: aluminium oxide, Al2O3
why is cracking necessary?
- Cracking converts long chain hydrocarbons into short chain hydrocarbons.
- Long-chain alkanes are broken down into alkanes and alkenes of shorter length.
- Crude oil contains a surplus long chains.
- Shorter chain hydrocarbons are in greater demand, e.g. petrol.
- Cracking also produces alkenes which are used in making polymers and ethanol.