4.5 Organic 1 Flashcards
What is crude oil made of?
mixture of hydrocarbons
What is a hydrocarbon?
compound made only of carbon and hydrogen
Why does crude oil have a range of boiling points?
different hydrocarbons
lots of shapes + sizes
What is the boiling point of refinery gases?
low
What is the boiling point of bitumen?
high
What happens to the boiling point when going down the table of hydrocarbons?
increases - more energy needed to break larger bonds
What is the molecular mass of refinery gases?
low
What is the molecular mass of bitumen?
high
What happens to the molecular mass when going down the table of hydrocarbons?
increases
What is the colour of refinery gases?
light
What is the colour of bitumen?
dark
What happens to the colour when going down the table of hydrocarbons?
darkens
What is the viscosity of refinery gases?
low
What is the viscosity of bitumen?
high
What are refinery gases used for?
fuel for home cooking
What is gasoline used for?
fuel for cars
What is kerosene used for?
fuel for aircraft
What is diesel used for?
fuel for trains
What is fuel oil used for?
fuel for ships
What is bitumen used for?
making roads
How do you remember the hydrocarbons?
Rithika’s Got
Gum
K?
Dude!
Frick Off
Biatch
How do you remember the uses of hydrocarbons?
Harriet Critchley
Came
Again
+
Touched
Sophie’s
Rabbits
What are the hydrocarbons?
Refinery Gases
Gasoline
Kerosene
Diesel
Fuel Oil
Bitumen
What are the uses of the hydrocarbon?
Home Cooking
Cars
Aircraft
Trains
Ships
Roads
What processes separates the fractions of crude oil?
fractional distillation
What is fractional distillation used for?
separating fractions of crude oil
Where is the fractional distillation column hottest?
at the bottom
Where is the fractional distillation column coldest?
at the top
How does the fractional distillation column work?
- crude oil vapours enter column
- rise until reaching BP where they condense
- different heights
- similar together
Where do the crude oil vapours condense after entering the column?
their boiling point
Why do crude oil vapours condense at different heights of the column?
different boiling points
What are fractions?
mixtures containing hydrocarbons that boil in a temperature range
What are alkanes?
hydrocarbons that fit general formula of CnH2n+2
What is a hydrocarbon?
compound of only carbon and hydrogen
What are alkanes made of?
simple molecules
What holds the molecules in alkanes together?
covalent bonds
How many carbons does methane have?
1 carbon
Which alkane has 1 carbon?
methane
How many carbons does ethane have?
2 carbons
Which alkane has 2 carbons?
ethane
How many carbons does propane have?
3 carbons
Which alkane has 3 carbons?
propane
How many carbons does pentane have?
5 carbons
Which alkane has 5 carbons?
pentane
How many carbons does butane have?
4 carbons
Which alkane has 4 carbons?
butane
What is displayed formula?
diagram showing positions of every atom and bond
What is structural formula?
structure of molecule in one line
What is molecular formula?
how many carbon and hydrogen there are
What is empirical formula?
simplest whole number ratio
What do homologous series share?
- chemical reactions
- physical properties
- same general formula
What are isomers?
molecules with same molecular formula but different structural formula
How many bonds can carbon make?
4
What are alkanes used for?
fuel
Why are alkanes used for fuel?
release a lot of energy
What does complete combustion produce?
carbon dioxide and water
What does incomplete combustion produce?
carbon monoxide and carbon
When does incomplete combustion occur?
not enough oxygen
What affect does incomplete combustion have on the alkane?
less effective as fuel - releases less energy
Which three significant pollutants does combustion of alkanes release to atmosphere?
carbon dioxide
nitrogen oxides
sulphur dioxide
Why is carbon dioxide a pollutant?
greenhouse gas
traps heat
climate change
Why is nitrogen oxide a pollutant?
dissolves rain water
acid rain
corrodes structures
harmful to plant and aquatic
Why is sulphur dioxide a pollutant?
dissolves rain water
acid rain
corrodes structures
harmful to plant and aqautic
When alkanes react with halogens what is the reaction called?
substitution
What does alkane + halogen reaction require?
UV light
Why is cracking useful?
short chains of alkanes more useful
What temperature is required for cracking?
650C
What catalyst is used for cracking?
aluminium oxide
What does cracking produce?
short alkane and alkene
What are alkenes?
hydrocarbons that fit general formula of CnH2n
Why are alkenes unsaturated?
one carbon double bond
How do alkenes differ to alkanes?
one carbon double bond
different formula
Which alkene has 2 carbons?
ethene
How many carbons does ethene have?
2 carbons
Which alkene has 3 carbons?
propene
How many carbons does propene have?
3 carbons
Which alkene has 4 carbons?
butene
How many carbons does butene have?
4 carbons
Which alkene has 5 carbons?
pentene
How many carbons does pentene have?
5 carbons
What are alkenes?
homologous series
How is isomerism different in alkenes?
can differ in more than one way
What are the two types of isomers for alkenes?
- branching of carbon chain
- position of carbon chain
Are alkenes saturated or unsaturated?
unsaturated
Why are alkanes saturated?
don’t have CC double bond
How do alkenes react with bromine?
carbon bond is broken and bromine atoms added in
What is the reaction between alkenes and bromine called?
addition
Does alkene + bromine require UV light?
no
What is the colour change for alkene + bromine ?
orange to colourless
Why does alkene + bromine go from orange to colourless?
orange bromine is used up in the reaction
When does an addition polymer form?
molecules of C=C double bond add into chains
What are the small molecules that add together called?
monomers
What is the long chain in addition polymers called?
polymer
What is poly(ethene) used for?
drinks bottles
shopping bags
What is poly(propene) used for?
storage boxes
climbing ropes
What is poly(chloroethene) used for?
wire insulation
drainpipes
What is poly(tetrafluoroethene) used for?
non stick coating
What is a property of addition polymers?
inert
What is the reactivity of addition polymers?
very unreactive
As addition polymers are inert and unreactive this means they…
…dont break down very easily
What are the options for disposal of addition polymers?
- reuse
- recycle
- incinerate
- landfill
Why do intermolecular forces break easily in small molecules?
weaker intermolecular forces
Why are intermolecular forces harder to break in large molecules?
stronger intermolecular forces
Why do large molecules have high boiling points?
strong intermolecular forces
Why do small molecules have low boiling points?
weak intermolecular forces
Why are shorter hydrocarbons easy to ignite?
lower boiling points, gas at room temp
Why are longer hydrocarbons hard to ignite?
higher boiling points, liquid at room temp
What does viscosity mean?
how easily a substance flows
Why do long hydrocarbons have a high viscosity?
stronger intermolecular forces
Why do short hydrocarbons have low viscosity?
weaker intermolecular forces