4.2 Covalent Bonding (4.2.0 - 4.2.3) Flashcards
Covalent Bonding Definition
A covalent bond is the electrostatic attraction between positively charged nuclei and shared pairs of bonding electrons.
How many bonding electrons are in a single covalent bond?
A single covalent bond consists of two shared bonding electrons, a double covalent bond consists of four shared bonding electrons and a triple covalent bond consists of six shared bonding electrons.
Bond length definition
Bond length is the distance between the nuclei of the bonded atoms.
How does a coordinate covalent bond differ from a ‘regular covalent bond’?
A coordinate covalent bond differs from a ‘regular’ covalent bond because both the bonding electrons come from one atom.
Dimer definition
A dimer is a larger molecule composed of two identical smaller molecules and can be linked by coordinate covalent bonds or by hydrogen bonds.
What kind of atoms can form a coordinate covalent bond?
Atoms in molecules that are electron-deficient (lacking in electrons) are able to form coordinate covalent bonds. An example of such a molecule is aluminium chloride. Despite being a metal and non-metal atom bonded together, the bonding in aluminium chloride is actually polar covalent, not ionic.
Difference in electronegativity ≥ 1.8 units is what kind of bond?
Ionic
Difference in electronegativity 0.5 − 1.7 units is what kind of bond?
Polar covalent
Difference in electronegativity 0.1 − 0.4 units is what kind of bond?
Non-polar (weakly polar) covalent
Difference in electronegativity 0 units is what kind of bond?
Pure covalent
Bond Dipole definition
A bond dipole is caused by the unequal sharing of electrons in a covalent bond.
Bonds between atoms with small differences in electronegativity have _ ionic character and _ covalent character.
Bonds between atoms with small differences in electronegativity have less ionic character and more covalent character.
The _ the electronegativity difference between the atoms, the _ the polarity of the bond and the _ its ionic character
The greater the electronegativity difference between the atoms, the greater the polarity of the bond and the greater its ionic character