4.1 Kinetics Flashcards

1
Q

What must happen in order for a reaction to happen?

A

The reactant particles must collide with each other with sufficient energy

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2
Q

What is the definition of activation energy?

A

The minimum amount of energy that colliding particles need to cause a reaction

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3
Q

What does [X] represent?

A

The concentration of X in moldm-3

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4
Q

What is zero order?

A

when the concentration of a reactant has no effect on the initial rate

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5
Q

What is first order?

A

When doubling the concentration causes the rate to also double

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6
Q

What is second order?

A

When doubling the concentration causes the rate to quadruple

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7
Q

How can the overall order of a reaction be determined?

A

By the sum of all the individual orders

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8
Q

How is the order of a reaction worked out?

A

By inspecting a table of experimental data or by plotting an appropriate graph

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9
Q

What is K?

A

The rate constant

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10
Q

What is the rate constant?

A

the constant of proportionality in the rate equation

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11
Q

What is the equation for working out rate?

A

Rate = k[A]^x [B]^y

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12
Q

What is the definition of the rate of a reaction?

A

The rate of a reaction is the decrease in concentration of reactants per unit of time, or the increase in concentration of products per unit of time

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13
Q

What are the units for rate?

A

moldm-3s-1

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14
Q

How is the value of the rate constant worked out?

A

The rate constant can be worked out using experimental data

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15
Q

What happens to the rate constant when temperature increases?

A

The rate constant also increases. This is due to the rate of reaction increasing due to the higher levels of particle energy

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16
Q

What is the effect of a catalyst on the rate constant?

A

Catalysts increase the rate constant. The rate constant may also decrease in an enzyme-catalysed reaction due to the enzyme denaturing past a certain temperature

17
Q

What does the rate of reaction depend on?

A

The rate determining step

18
Q

What happens when a reagent has order 0?

A

It is not included in the rate determining step

19
Q

What happens to the steps after the rate determining step?

A

They are not included in the rate equation