4: Testing Materials_checked Flashcards
What are the properties of ceramics?
Hard - difficult to scratch
Brittle - easily shatter into pieces due to rigid structure/ cracks spread through them when they break
Stiff - difficult to stretch or bend due to strong bonds between atoms.
Describe structure of a ceramic.
The arrangement of atoms in a ceramics can be crystalline or poly-crystalline [where there are any regions or grains of crystalline structure. The atoms in each grain line up in the same direction.
Some ceramics like glass are amorphous - there is no pattern; the atoms are arranged at random. The quicker a molten a material is cooled, the more likely it is to be amorphous.
The random atomic bonding means there is no slips planes in ceramic lattices. They also don’t have dislocations which can move meaning that ceramic materials rarely plastically deform before they fracture. The rigid structure means that ceramics are very brittle materials.
The ceramics are either ionically or covalently bonded in a giant rigid structure. The strong bonds between atoms make ceramics stiff.
Ceramics being brittle is why cracks spread through them when they fracture, because the applied force acts over a very small area so the stress is high
Describe the properties of Metals
Some metals are malleable (can be shaped easily) and some are ductile (can be drawn into wires) this is due to the dislocations (missing atoms in metal structure) allowing planes (rows) of metal atoms to slip over each other when a force is applied
Some metals are stiff - strong metallic bonds between ionic lattice and delocalised electrons
Metals are good conductors - metals have a sea of delocalised electrons that allows metals to conduct electricity
Metals are tough: it absorbs a lot of energy (deforms plastically) per unit area before fracture. This is because when you apply a stress the metal deforms plastically in the region of the crack, making the crack broader reducing stress around it
Describe the structure of Metals
Metals consist of crystalline metallic lattice - atoms are arranged in a regular repeating pattern; surrounded by a sea of delocalised or free electrons
PIC: What happens when you apply a force to a metal with dislocations?
When a force is applied to a metal, the inter-atomic spacing between the ions increases. This increase is unform during elastic deformation. Once the stress is high enough to cause plastic deformation, the planes [sheets of metal ions] within the metal slip over each other. If there is a dislocation in the metal, the stress needed to cause slipping is lower than the stress needed to cause slipping in a perfect metal.
What happens when you put the atoms of a second metal in dislocations?
What is this process called?
What’s the effect?
Atoms of a second metal (impurities) can be placed inside dislocations to pin them down. This increases the stress needed to cause slipping.
This process is called alloying.
This causes metals to be harder and less ductile
What is a perfect metal?
A metal lattice with no dislocations (missing atoms) or impurities.
What is a polymer?
Name 2 types of polymers.
A polymer is a long molecular chain, made up of single repeating units called monomers
There are man made polymers (polythene) and natural polymers (rubber)
Give an example of a polymer
Rubber: sulfur atoms form cross links with the polymer chains; the more sulfur that is added, the more cross links that are formed and the stiffer the rubber [polymer] becomes.
PIC: Structure and bonding of a polymer
- The monomers in a chain are covalently bonded so they’re very hard to separate.
- Polymer chains are often entangled but can be unravelled by rotating about their bonds when you pull them. This makes polymers flexible.
- The strength and number of bonds between the chains also affects the polymer’s flexibility. if the cross link bonds (chains tied at regular interval) are stronger and you have more of them, the more rigid the polymer
What is Hooke’s law equation?
What is the constant a measure of?
For small extensions, the force, F, is proportional to the extension, x
F = kx
F = force, in Newtons
x = extensions, in metres
k = constant of proportionality (spring constant), Nm-1
The spring constant is a measure of stiffness
k is small when small force gives big extension
k is big when big force gives small extension
PIC: PRACTICAL: Force Extension graph for a rubber band - explain the process.
- Start with the shown apparatus,
- Use a stiff wire wrapped around the bottom of the mass to provide a pointer.
- Measure the unstretched length of the band
- Then measure the length of the band with each mass you add on find the extension by subtracting old length from new length.
- Remove each mass and record the extension
- Plot graph of Force on y-axis and extension on x-axis
What is material compression?
What is the force called when you stretch a material
Compression occures when you squash a material.
Stretching forces are also called tensile forces.
What is elastic deformation for a wire?
When you deform a wire but it returns to its original length when the force (stress) is removed
PIC: What is the elastic limit, E?
Up to the elastic limit, an object will elastically deform; beyond the elastic limit, it will plastically deform.
What is plastic deformation for a wire?
A wire that has been stretched beyond its elastic limit. The wire is permanently deformed and will not return to its original length when the stress (force) is removed
PIC: What is the fracture stress, B?
The stress at which the object breaks. It is the point after plastic deformation at which the object breaks. At this point, the stress becomes so great that atoms separate completely and the material [object] breaks.
PIC: What is the limit of proportionality, P?
The point before the elastic limit where the graph is straight and extension is proportional to the force