4-Chemical Changes Flashcards

1
Q

What is an acid?

A

A substance that forms an aqueous solution with a pH less than 7 and forms H+ ions in water.

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2
Q

What is an alkali?

A

A base that dissolves in water with a pH greater than 7. Forms OH- ions in water.

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3
Q

What is a base?

A

Substance with a pH greater than 7

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4
Q

What would be considered a strong acid?

A

pH 1-3, completely ionised in aqueous solution.

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5
Q

Give three examples of strong acids.

A

Examples of strong acids are hydrochloric, nitric and sulfuric acids.

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6
Q

What is a weak acid?

A

pH 3-6, only partially ionised in aqueous solution

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7
Q

Give three examples of weak acids.

A

Examples of weak acids are ethanoic, citric and carbonic acids.

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8
Q

What is the reaction between acids and bases?

A

Neutralisation - acid + base -> salt + water

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9
Q

What is the neutralisation reaction in terms of H ions?

A

Hydrogen ions rect with hydroxide ions to produce water,
H+ + OH- ->H20

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10
Q

Examples of pH1 acids?

A

Car battery acid, stomach acid

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11
Q

Examples of pH3 acids?

A

Vinegar, lemon juice

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12
Q

Examples of pH4 acids?

A

Acid rain

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13
Q

What happens to the rate of reaction when theres a higher concentration of H+ ions?

A

If concentration of H+ ions is higher, rate of reaction will be faster, so strong acids will be more reactive than weak acids.

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14
Q

How is concentration of pH measured and tested?

A

Concentration of H+ ions in a solution, tested by universal indicator or a pH probe.

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15
Q

When pH decreases by a factor of 1, what does H+ ions increase by?

A

10

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16
Q

What is the rule for changing pH and concentration of H+ ions?

A

Factor of H+ ion concentration changes by 10^-x
(x is the difference of pH)

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17
Q

What is the reaction of metal oxides and metal hydroxides with acids?

A

All metal oxides and metal hydroxides react with acids to form a salt and water.
Acid + metal oxide -> salt + water
Acid + metal hydroxide -> salt + water

18
Q

Reaction of acids with metals?

A

Acids react with some metals to produce salt and hydrogen.

19
Q

Whats the reaction of acids and metal carbonates?

A

Acids and metal carbonates react to produce salts, water and carbon dioxide.

20
Q

What does the salt produced depend on?

A

The salt produced depends on the acid used and the positive ions in the base, alkali or carbonate.

21
Q

How can soluble salts be made?

A

•Reacting acids with solid, insoluble bases
•eg. metals, metal oxides, hydroxides, carbonates.

22
Q

What is the reactivity series?

A

How well a metal reacts, their reactivity towards other substances.

23
Q

How is the reactivity of a metal determined?

A

How easily they lose electrons to form positive ions.

24
Q

What is the order of elements in the reactivity series?

A

Potassium-K
Sodium-Na
Lithim-Li
Calcium-Ca
Magnesium-Mg
Carbon-C
Zinc-Zn
Iron-Fe
Hydrogen-H
Copper-Cu

25
Q

How would a very reactive metal e.g Potassium, sodium, lithium, calcium react with a dilute acid?

A

Vigorously and explosively, moving quickly, lots of bubbles/fizzing and hydrogen given off.

26
Q

How would a fairly reactive metal e.g magnesium react with a dilute acid?

A

Vigorously, loads of bubbles produced

27
Q

How would a not very reactive metal e.g zinc or iron react with a dilute acid?

A

React slowly with a cold acid but more strongly if you heat them up.

28
Q

What is oxidisation?

A

Metals reacting with oxygen to produce metal oxides - gain oxygen. Electrons are lost.

29
Q

What is reduction?

A

Loss/ removal of oxygen. Electrons are gained.

30
Q

How can metals be extracted from their oxides/

A

Metals less reactive than carbon can be extracted from their oxides by reduction with carbon. Metals more reactive extracted with electrolysis.

31
Q

What does electrolysis mean?

A

Splitting up with electricity

32
Q

How does electrolysis work?

A

*Ionic compounds melted or dissolved are free to move around and conduct electricity
*Electric current passed through electrolytes causing ions to move to electrodes
*Positive move to negative cathode
*Negative move to positive anode
*Ions discarded at electrodes to produce elements

33
Q

What happens when a simple ionic compound is electrolysed in a molten state?

A

*Metal is produced at the cathode
*Non-metal produced at the anode

34
Q

What are the disadvantages of using electrolysis to extract metals?

A

*Large amounts of energy used
*Positive carbon anode needs to be continuously replaced

35
Q

What can be produced at the negative cathode and under what conditions?

A

Hydrogen produced if metal more reactive than Hydrogen.

36
Q

What can be produced at the positive anode and under what conditions?

A

Oxygen unless solution contains halide ions when halogen produced

37
Q

What are the uses of aluminium and its alloys?

A

•Pans
•overhead power cables
•cooking foil
•drink cans
•bicycle frames and car bodies

38
Q

What is the equation for the electrolysis of aluminium oxide?

A

Aluminium oxide –> aluminium + oxygen

39
Q

What is the half equation at the cathode?

A

Al3+ + 3e- –> Al

40
Q

What is the half equation at the anode for extraction of aluminium?

A

2O^2- –> O2 + 4e

41
Q

How is aluminium extracted from aluminium oxide?

A

•electrolysis of aluminium oxide mixed with molten cryolite
•to lower melting point and reduce energy needed
•aluminium formed at negative cathode
•oxygen produced at positive anode