4-1) Batteries & Battery Maintenance Flashcards
What were the first electrical storage devices?
Large capacitors called laden jars
How does a battery store energy and how is a battery constructed?
A battery stores energy in the form of electrical potential energy that is held in solution. A battery is constructed of a set of metal plates that can attract and repel electrons. The electrons are held in solution in a dielectric that surrounds the metal plates.
What is a voltaic pile and who came up with it and when?
Alessandro Volta invented the first battery as a voltaic pile in 1800. He made his battery with a stack of alternating layers of zinc, blotting paper soaked in salt water and silver. The top and bottom layers of the pile must be different metals. If you attach a wire to the top and bottom of the pile, you can measure a voltage and a current from the pile.
What feature divides batteries into two basic categories?
Their ability to recharge or not.
What is a primary battery?
A primary battery cannot be recharged, due to the deterioration of the material in its construction from normal discharge. Most small batteries purchased from a store for small electronics are classified as primary cells.
What is a secondary battery?
A secondary battery cell is designed to be recharged. Charging is accomplished by applying a voltage higher than that of the cell to the cell terminals. The higher voltage to the cells is reverse flow and charges the battery that causes a change in ions inside the battery. The electrons flow out of solution and back to the metal plates of the battery.
What is a wet cell battery?
Liquids are used for electrolytes as opposed to modern dry cells.
What is a Daniell cell and what could it be used for?
The Daniell cell is a wet cell battery invented in the 1800s consisting of copper and zinc plates and copper and zinc sulfates. It could be used for stationary applications.
What are 3 other names for the Daniell cell battery?
- Crowfoot cell–because of the typical shape of the zinc electrode
- Gravity cell–because gravity keeps the two sulfates separated
- Wet cell–because it uses liquids for the electrolytes as opposed to the modern dry cell
What is a voltaic cell?
Plates of dissimilar metals are placed in a chemical solution called an electrolyte, opposite electric charges are established between the two plates. When a rod of carbon and a plate of zinc are placed in a solution of ammonium chloride, the result is an elementary voltaic cell. The carbon and zinc elements are called electrodes. The carbon is the positively charged anode, the zinc is the negatively charged cathode. The combination of the two surrounded by the electrolyte for a battery cell.
What happens when two electrodes are connected by an external conductor?
Free electrons from the zinc plate (negative terminal) will flow to the carbon rod (positive terminal), and hydrogen ions move to the carbon rod, where each ion pics up one electron and because a neutral hydrogen atom.
What is the process of polarization in a wet cell battery?
Hydrogen gas bubbles form on the carbon rod and insulate it from the electrolyte solution. This process is called polarization and will cause the current flow to stop until the hydrogen is removed.
How do dry cell batteries mitigate polarization?
Dry cell batteries employ a compound called manganese dioxide (MnO2) to prevent accumulation of hydrogen at the positive electrode in the cell. In a dry cell battery, the electrolyte is in the form of a paste.
How is a primary dry cell constructed?
Dry cell batteries employ a compound called manganese dioxide (MnO2) to prevent accumulation of hydrogen at the positive electrode in the cell. In a dry cell battery, the electrolyte is in the form of a paste. The surrounding case is made from zinc, which acts as a negative electrode. The space between the carbon rod and the zinc can be filled with manganese dioxide saturated with electrolyte to reduce the internal resistance of the cell. The top of the cell is sealed with a wax compound to prevent leaking and dry electrolyte.
What is the typical voltage developed by a carbon zinc dry cell?
1.5 volts, but voltage of any cell depends on the materials used as the electrodes.
What is the typical voltage developed by a lead-acid secondary cell, such as those employed in storage batteries?
2.1 volts.
What determines if an alkaline cell is a rechargeable secondary or non-rechargeable primary?
The electrode materials
What is the typical voltage produced by most common alkaline battery cells?
1.5 volts
Where are mercury cells most often used?
Mercury cells are used for small button batteries found in miniature equipment such as watches and calculators.
How are nickel-cadmium cells constructed?
They have been developed to a high degree of efficiency and dependability. The electrodes are welded together (sintered).
Anode is nickel or nickel carbonyl and the cathode is cadmium.
What is the advantage of a Ni-Cad battery?
The cells can remain in a discharged condition indefinitely at normal temperatures without degradation.
What would happen if a lead acid battery is left in a discharged condition for extended periods?
Sulfation of the plates occurs, and the cells lose much of their capacity.
How does peak power of a Ni-Cad battery compare with a lead-acid battery?
A Ni-Cad battery has tremendous peak power and delivers far more power than a lead-acid battery of the same size and weight.
How does peak power of a Ni-Cad battery compare with a lead-acid battery?
A Ni-Cad battery has tremendous peak power and delivers far more power than a lead-acid battery of the same size and weight.