3rd LE Flashcards
The calorimeter is a device used to measure * that accompany a physical or a chemical process.
heat changes
The * measured from a process conducted under * is referred to as enthalpy,
heat, constant pressure
Retention factor: * parameter
B. Basis of separation: *
C. Stationary phase: *
D. Type of system: *
qualitative
Polarity
water adsorbed in the chromatographic paper
Close
Chromatography is technique used to separate components of a mixture based on differences in *
intermolecular forces of attraction
Paper chromatography is a chromatographic technique where the stationary phase is the * while the mobile phase is the * which can either be polar or nonpolar.
water bound to the cellulose of the paper
solvent
Given a specific stationary and mobile phase, a component will always have the * retention factor (Rf). The retention factor is defined as the * which is retained in the *
same
fraction of a component
mobile phase
endothermic (ΔHsoln = +),
exothermic (ΔHsoln = -)
* (ΔHsoln = 0).
This value will be dependent on the relative strengths of the * between like and unlike particles
athermic
interparticle forces of attraction
Stronger forces of attraction between unlike particles result in an overall * in the volume of solution; otherwise an overall * in the volume of solution is observed.
contraction
expansion
Glycerol – *
Naphthalene – *
polar
nonpolar
chromatography (based on differences in * and ability to be * ), and distillation (based on differences in * or * of the mixture components)
solubility, adsorbed
volatility, boiling point
simple distillation, which is typically used for two * liquids with boiling points that are * and far from each other.
miscible, below 150 °C
- (for isopropyl alcohol) or about * (for ethyl alcohol).
82 to 84 °C
78 to 80 °C
where Ptrapped air is the pressure of gas * , Pbar is the *
trapped in the eudiometer
barometric pressure
For all cases, the pressure of gas produced in dry conditions can be calculated as
𝑃𝑑𝑟𝑦 𝑎𝑖𝑟 = 𝑃𝑡𝑟𝑎𝑝𝑝𝑒𝑑 𝑎𝑖𝑟 − 𝑃𝑤𝑎𝑡𝑒𝑟 𝑣𝑎𝑝𝑜𝑟
Colligative properties are properties of solutions which depend on the * of the * solutes
concentration, non-volatile