3.5 Lipids Flashcards

1
Q

What elements do lipids contain?

A

Carbon, hydrogen, oxygen

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2
Q

Are lipids considered as polymers?

A

No, not made up of long chains of monomers

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3
Q

What is the role of lipids?

A

-Energy supply - can be oxidised to provide energy to cells
-Structural components - phospholipids are used in cell membranes
-Waterproofing - insoluble lipoids are used to form water-resistant barriers
-Insulation - help retain heat or act as electrical insulators
-Protection - delicate organs surrounded by a layer of fat

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4
Q

What are lipids?

A

Macromolecules

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5
Q

What are macromolecules?

A

Large complex molecules with as large weight

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6
Q

Are lipids soluble in water?

A

No, as they are non-polar, electrons distributed evenly, no positive or negative areas within the molecule

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7
Q

What is the structure of a triglyceride?

A

-One glycerol molecule with three fatty acid tails
-Each fatty acid tail contains a hydrocarbon chain (R) which can vary in length
-Both glycerol and fatty acid groups contain OH groups which interact

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8
Q

What is the name of the bond in lipids?

A

Ester bond

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9
Q

What is esterification another example of?

A

A condensation reaction

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10
Q

What are the properties and function of triglycerides?

A

-Fatty acid chains are hydrophobic which makes them insoluble
-Long hydrocarbon tails = many carbon-hydorgen bonds can be broken to release energy
-Low mass to energy ration = lots of energy can be stored in a small volume
-Insoluble = do not affect water potential as they are large and non-polar
-High ration of hydrogen to oxygen atoms = release water when oxidised

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11
Q

What is meant by hydrophilic?

A

Section of a molecule which is attracted to water

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12
Q

What is meant by hydrophobic?

A

Section of a molecule which is repulsed to water

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13
Q

What happens when a triglyceride undergoes a condensation reaction?

A

-The hydroxyl groups on the glycerol and on the 3 fatty acids react together to release 3 water molecules
-Results in three ester bonds between the glycerol and the fatty acids

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14
Q

What happens when a triglyceride undergoes a hydrolysis reaction?

A

-The addition of three water molecules breaks the ester bonds
-This separates the glycerol and the fatty acids

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15
Q

What is the structure of a phospholipid?

A

-Hydrophilic head, containing glycerol molecule and a phosphate group
-Hydrophobic tail - containing 2 fatty acids tails

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16
Q

What is the function of triglycerides?

A

Energy store

17
Q

What elements do phospholipids contain?

A

Phosphorous, carbon, hydrogen, oxygen

18
Q

What bonds are in phospholipids?

19
Q

How phospholipids react with water?

A

-Non-polar fatty acid tail which is hydrophobic
-Charged heads are polar and are attracted to water, are hydrophilic
-When placed in water, arrange themselves in a bilayer, hydrophilic heads facing out towards water, and hydrophobic tails facing in away from water

20
Q

What is the uses of phospholipids?

A

Membranes, hormones (eg. testosterone)

21
Q

What are the two types of fatty acids?

A

Saturated and unsaturated

22
Q

What are saturated fatty acids?

A

-Fully saturated with hydrogen, all carbon atoms are bonded to the maximum number of hydrogen atoms
-No carbon-carbon double bonds
-Have higher melting points, usually solid at room temperature

23
Q

What is it called is there is one double bond in a hydrocarbon chain?

A

Monounsaturated

24
Q

What is it called is there is two or more double bonds in a hydrocarbon chain?

A

Polyunsaturated

25
What are unsaturated fatty acids?
-Hydrocarbon chains do not contain the maximum number of hydrogen atoms -Hydrocarbon chain has at least one carbon-carbon double bond, which causes the chain to kink or bend and therefore cannot pack as closely together -Makes lipids have lower melting points and so are liquids are room temperature, (oils)
26
What is the name of the test for lipids?
Emulsion test
27
Describe the steps of the emulsion test
1. Place 4cm3 of food sample in a test tube 2. Using a dropping pipette add 2cm3 of ethanol 3. Shake 4. Add 2cm3 of distilled water, shake for 1 minute 5. If lipids are present, a milky white emulsion will appear
28
What are sterols and their function?
-Complex alcohol molecules based on a 4 carbon structure -Dual hydrophilic/hydrophobic characteristics like phospholipids eg. cholesterol
29
What is cholesterol and its function?
-Made in liver and intestines -Formation of cell membranes, becoming positions between the phospholipids with the hydroxy group at the periphery of the membrane -Adds stability to membrane, regulates their fluidity
30