3.2.1 Periodicity Flashcards
How are elements in periodic table arranged?
Increasing proton number
What block are group 1 and 2 elements?
S-block
What block are group 3-0 elements?
p-block
What block are transition elements?
d-block
How does atomic radius change across period 3, why?
The number of protons increases however shielding remains constant. Leads to a greater electrostatic attraction between nucleus and outermost electron. So the atomic radius decreases.
Define first ionisation energy?
Energy required to remove the outermost electron from one mole of gaseous atoms to form one mole of gaseous ions.
What factors affect the ionisation energy?
Atomic radius
Amount of shielding
Nuclear charge
State the trend in ionisation energy across period 3.
Ionisation energy Increases, number of protons increases but shielding remains the same so increasing electrostatic attraction between outermost electron and the nucleus.
State the trend in ionisation energy down a group.
Ionisation energy decreases, the amount of inner energy level shielding increases so the amount of electrostatic attraction to the nucleus decreases.
Why is there a drop in ionisation energy between group 2 and 3?
In group 3 each element has an electron in the P-sublevel. In group 2 the outermost electron is in the s-sublevel. P-sublevel is higher in energy so requires less energy to remove the outermost electron compared to s-sublevel.
Why is there a drop in ionisation energy between group 5 and 6?
The 4th electron has to enter an already half filled p-orbital causing electrons to pair up. This leads to an electron pair repulsion which makes it easier to remove the fourth outer electron.