3.1.5 - Kinetics Flashcards
1
Q
Temperature effect on Maxwell-Boltzmann distribution
A
- Peak shifts to the right
- Peak is lower
- Area under >Ki is increased
2
Q
Pressure effect on rate of reaction
A
- Increased ROR
- Particles closer together
- More frequent succesful collisions
3
Q
Concentration effect
A
- Increased ROR
- More particles, more frequent sucessful collisions
- Higher chance of reaction
Area under graph changes
4
Q
3 ways of measuring rate of reaction
A
- Precipitate formation (cross under flask)
- Amount of mass (gas lost)
- Volume of gas produced (gas syringe)
5
Q
Catalyst definition
A
Increases ROR without being used up. Provides alternate reaction pathway with lower activation energy.
6
Q
What happens if you remove half the reactant?
A
Halve the line on the graph
7
Q
Large excesses and ROR relationship
A
- Concentration change is negligible
- No effect on ROR
8
Q
order with respect to a reactant
A
0 = Constant gradient as H+ decreases