3.1.3.7 Forces between molecules Flashcards

1
Q

the strongest type of interaction that occurs between molecules of hydrogen peroxide and water

A

Hydrogen bond(ing) / H bonding / H bonds

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2
Q

in terms of electronegativity, why the boiling point of H2S2 is lower than H2O2

A

Electronegativity of S lower than O or electronegativity difference between H and S is lower
No hydrogen bonding between H2S2 molecules Or only van der Waals / only dipole-dipole forces between H2S2 molecules

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3
Q

the strongest attractive force between two ammonia molecules

A

Hydrogen bonds / H bonds

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4
Q

the strongest type of intermolecular force in how the strongest type of intermolecular force in liquid HF arises (CH4)

A

Van der Waals/ vdw/London/ temporary (induced) dipole/ dispersion forces

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5
Q

the strongest type of intermolecular force in Ammonia (NH3)

A

Hydrogen bonds/H bonds

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6
Q

strongest type of intermolecular force present in Liquid F2

A

van der Waals’ / induced/temporary dipole-dipole / dispersion / London forces

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7
Q

strongest type of intermolecular force present in Liquid CH3F

A

dipole-dipole

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8
Q

strongest type of intermolecular force present in Liquid CH3F

A

hydrogen bonding

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9
Q

how the strongest type of intermolecular force in liquid HF arises

A

large difference in electronegativity between H and F / F most/very/much more electronegative
δ+H-Fδ- dipole created or dipole clearly implied
attraction/bond formed between δ+H and lone pair on F

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10
Q

the trend in the boiling points of the hydrogen halides from HCl to HI

A

van der Waals’ / induced/temporary dipole-dipole / dispersion / London forces / attractions
increase with the increasing Mr / size / mass / N 0 of e- / size of e- cloud (in the hydrogen halides)

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11
Q

reason why the boiling point of HF is higher than that of all the other hydrogen halides

A

hydrogen bonding stronger than van der Waals’ attraction/forces

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12
Q

why the boiling point of methanol is much higher than that of oxygen

A

van der Waals’ forces between oxygen molecules
Hydrogen bonding between methanol molecules
H-B stronger than van der Waals’ OR stronger IMF in methanol

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13
Q

in terms of the intermolecular forces present in each compound, why HF has a higher boiling point than HCl

A

HF = hydrogen bonding
HCl = (permanent) dipole-dipole bonding or even van de Waals’
Hydrogen bonding stronger / is the strongest IMF

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14
Q

the strongest type of intermolecular force between hydrogen fluoride molecules

A

Hydrogen bonds/hydrogen bonding/H bonds/H bonding

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15
Q

why the boiling point of fluorine is very low

A

vdw / van der Waals forces between molecules

IMF are weak / need little energy to break IMF / easy to overcome IMF

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16
Q

the structure of and bonding in graphite and explain why the melting point of graphite is very high

A

Layers of (C atoms)
Connected by covalent bonds within each layer
Van der Waals forces/IMF between layers/weak forces between layers
Many/strong covalent bonds need to be broken

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17
Q

why iodine vaporises when heated gently

A

Van der Waals forces are weak or easily broken

Van der Waals between molecules (or implied)

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18
Q

the strongest type of intermolecular force in water

A

Hydrogen/H bonds

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19
Q

the strongest type of intermolecular force in hydrogen sulfide (H2S)

A

van der Waals/vdw/dipole-dipole/London/temporarily induced dipole/dispersion forces

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20
Q

why the boiling point of water is much higher than the boiling point of hydrogen sulfide

A

Hydrogen bonds/IMF (in water) stronger
OR IMF/VDW/dipole-dipole forces (in H2S) are weaker
OR H bonding is the strongest IMF

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21
Q

why the boiling points increase from H2S to H2Te

A

Atoms/molecules get larger/more shells/more electrons/more surface area
therefore increased Van der Waals/IMF forces

22
Q

three types of intermolecular force

A

Van der Waals’
dipole – dipole
hydrogen bonding

23
Q

Why hydrogen fluoride requires more heat energy for melting than does hydrogen chloride

A

H-Bonding in HF
(dipole-) dipole/V dW in HCl
H-bonding is stronger than dipole-dipole or V.dW

24
Q

Why hydrogen iodide requires more heat energy for melting than does hydrogen chloride

A

HI bigger molecule than HCl

Therefore the forces between HI molecules are stronger

25
why diamond and iodine (solid) have different melting points
Iodine Weak van der Waals’ forces / induced dipole-induced dipole Diamond Covalent bonds would need to be broken Many / strong covalent bonds OR much energy needed
26
the strongest type of intermolecular force between hydrogen fluoride molecules
Hydrogen bonding
27
Why HI molecules don’t have hydrogen bonding like HF molecules
Fluorine more/very electronegative or iodine less electronegative or electronegativity difference too small in HI HI dipole weaker or bonding e– more equally shared
28
the strongest attractive force between two ammonia molecules
Hydrogen bonds / H bonds
29
why iodine has a higher melting point than fluorine
Iodine has more electrons / iodine is bigger (atom or molecule) / iodine has bigger Mr / bigger surface area Stronger / more van der Waals forces / vdw / London / temporarily induced dipole / dispersion forces between molecules
30
the strongest type of intermolecular force in a sample of NHF2
Hydrogen bonds
31
Although phosphine molecules contain hydrogen atoms, there is no hydrogen bonding between phosphine molecules. Suggest an explanation for this.
Difference in electronegativity between P and H is too small
32
the strongest type of intermolecular force holding the water molecules together in the ice crystal
Hydrogen bonding
33
the strongest type of intermolecular force in methane
Van der Waals’/VdW
34
reason why the melting point of ice is higher than the melting point of methane
Hydrogen bonding is stronger (than van der Waals forces)/IMF in ice stronger (than IMF in methane)/H bonds take more energy to break
35
the strongest type of intermolecular force between CCl2F2 molecules
Dipole – dipole
36
why the boiling point of water is much higher than the boiling point of hydrogen sulfide
Hydrogen bonds/IMF (in water) stronger IMF/VDW/dipole-dipole forces (in H2S) are weaker H bonding is the strongest IMF
37
why the boiling points increase from H2S to H2Te
Atoms/molecules get larger/more shells/more electrons/more surface area therefore increased Van der Waals/IMF forces
38
the strongest type of intermolecular force in Methane (CH4)
Van der Waals/ vdw/London/ temporary (induced) dipole/ dispersion forces
39
the strongest type of intermolecular force in Ammonia (NH3)
Hydrogen bonds/H bonds
40
how the strongest type of intermolecular force arises between two molecules of ammonia
(Large) electronegativity difference between N + H/ N very electronegative; Forms N δ– / H δ+ or dipole explained in words Lone pair on N attracts/forms weak bonds with H (δ+)
41
why HF has a higher boiling point than HCl
HF = hydrogen bonding HCl = (permanent) dipole-dipole bonding or even van de Waals’ Hydrogen bonding stronger / is the strongest IMF
42
the strongest type of interaction that occurs between molecules of hydrogen peroxide and water
Hydrogen bond(ing) / H bonding / H bonds
43
why the boiling point of H2S2 is lower than H2O
Electronegativity of S lower than O or electronegativity difference between H and S is lower No hydrogen bonding between H2S2 molecules Or only van der Waals / only dipole-dipole forces between H2S2 molecules
44
the strongest attractive force between two ammonia molecules
Hydrogen bonds / H bonds
45
the strongest type of intermolecular force between hydrogen fluoride molecules
Hydrogen bonds/hydrogen bonding/H bonds/H bonding
46
the strongest type of interaction between polymer chains of Kevlar
Hydrogen bond(ing)
47
the strongest type of intermolecular force between one molecule of ammonia and one molecule of water
Hydrogen bonding / hydrogen bonds / H-bonding / H-Bonds
48
Phosphine (PH3) has a structure similar to ammonia. In terms of intermolecular forces, suggest the main reason why phosphine is almost insoluble in water.
(Phosphine) does not form hydrogen bonds (with water)
49
why iodine has a higher melting point than fluorine
Iodine has more electrons / iodine is bigger (atom or molecule) / iodine has bigger Mr / bigger surface area Stronger / more van der Waals forces / vdw / London / temporarily induced dipole / dispersion forces between molecules
50
the strongest type of intermolecular force in a sample of NHF2
Hydrogen bonds
51
why the boiling point of methanol is much higher than that of oxygen
van der Waals’ forces between oxygen molecules; Hydrogen bonding between methanol molecules; H-B stronger than van der Waals’ OR stronger IMF in methanol;
52
why the boiling point of H2S2 is lower than H2O2
Electronegativity of S lower than O or electronegativity difference between H and S is lower No hydrogen bonding between H2S2 molecules Or only van der Waals / only dipole-dipole forces between H2S2 molecules