3.1.2 Carbohydrates Flashcards

1
Q

(Carbohydrates) What monomers make up carbohydrates?

A

Monosaccharides

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2
Q

(Carbohydrates) What are three examples of monosaccharides?

A

Glucose, fructose and galactose.

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3
Q

(Carbohydrates) Glucose is a hexose sugar, what is a hexose sugar?

A

A monosaccharide with six carbon atoms in each molecule.

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4
Q

(Carbohydrates) Alpha and beta glucose are isomers. What is an isomer?

A

A molecule with the same molecular formula as each other, but with the atoms connected in a different way.

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5
Q

(Carbohydrates) When is a disaccharide formed?

A

When two monosaccharides join together by condensation reactions.

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6
Q

(Carbohydrates) What type of bond is formed when monosaccharide join together?

A

A glycosidic bond forms between the two monosaccharides as a molecule of water is released.

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7
Q

(Carbohydrates) Surcose is a disaccharide formed a condensation reaction between what two molecules?

A

A glucose molecule and a fructose molecule.

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8
Q

(Carbohydrates) Lactose is a disaccharide formed between what two molecules?

A

A glucose molecule and a galactose molecule.

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9
Q

(Carbohydrates) When is a polysaccharide formed?

A

When more than two monosaccharides are joined together by a condensation reaction.

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10
Q

(Carbohydrates) What can polysaccharides be broken down into?

A

Into their constituent monosaccharides by hydrolysis reactions.

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11
Q

(Carbohydrates) Where do cells get energy from?

A

Glucose

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12
Q

(Carbohydrates) What two polysaccharides of alpha-glucose is starch a mixture of?

A

Amylose and amylopectin

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13
Q

(Carbohydrates) Is starch soluble or insoluble in water?

A

Insoluble

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14
Q

(Carbohydrates) Starch is insoluble in water and doesn’t affect water potential, so was doesn’t it cause?

A

It doesn’t cause water to enter the cells by osmosis, which would make them swell - good for storage.

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15
Q

(Carbohydrates) Describe the structure of the polysaccharide ‘amylose’.

A
  • Long, coiled, unbranched chain of alpha-glucose
  • Angles of glycosidic bonds give it a coiled structure
  • Which makes it compact: good for storage
  • Glycosidic C1-4 bonds formed through condensation reaction
  • Polymer of alpha glucose
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16
Q

(Carbohydrates) Describe the structure of the polysaccharide ‘amylopectin’.

A
  • Long, branched chain of (polymer of) alpha-glucose
  • Glycosidic C1-4 bonds form chains with C1-6 side branches
  • Side branches allow enzymes that break down the molecule to get the glycosidic bonds easily, glucose can be released easily
17
Q

(Carbohydrates) What do animal cells store excess glucose as?

18
Q

(Carbohydrates) Describe the structure of the polysaccharide ‘glycogen’.

A
  • Similar structure to amylopectin, but with more side branches
  • Loads of branches means that glucose stored can be released quickly (important for energy release)
  • Glycosidic C1-4 bonds from chains with C1-6 side branches
  • Very compact molecule, good for storage
  • Insoluble
19
Q

(Carbohydrates) Describe the structure of the polysaccharide ‘cellulose’.

A
  • Fibrous
  • Unbranched
  • Provides structure in plants
  • Consists of several thousand beta-glucose joined together in a long straight chain by beta 1-4 glycosidic links
20
Q

(Carbohydrates) What happens when beta-glucose molecules bond in cellulose?

A

Form straight cellulose chains that are linked together with hydrogen bonds to form microfibrils.

21
Q

(Carbohydrates) What do microfibrils provide in cellulose?

A

Structural support for cells.

22
Q

(Carbohydrates) Describe the food test for starch.

A

Add 2cm3 of iodine in a potassium iodine solution. Colour change from orange to blue/black.

23
Q

(Carbohydrates) Maltose is a disaccharide formed by a condensation reaction was what two molecules?

A

Two glucose molecules

24
Q

(Carbohydrates) What are the 4 functions of monosaccharides?

A
  • Source of energy in respiration
  • Building blocks for much larger polysaccharide molecules - starch, glycogen, cellulose, chitin
  • Required to build nucleotides (deoxyribose in DNA, ribose in RNA, ATP)
  • Intermediates in biochemical reactions
25
(Carbohydrates) How are monosaccharides a source of energy in respiration?
C-C and C-H bonds break to form CO2 and water, realising energy to make ATP.
26
(Carbohydrates) What do disaccharides form?
1-4 glycosidic bonds
27
(Carbohydrates) Describe the formation of maltose. (4)
- 2 alpha glucose molecules - Condensation reaction - A water molecule is released - Forming a C1-C4 glycosidic bond
28
(Carbohydrates) Describe the test for reducing sugars.
- Add 2cm3 Benedict’s solution to the sample - Heat in water bath, 90 degrees for 5 mins - Colour change from light blue to red/orange precipitate
29
(Carbohydrates) Is maltose (x2 alpha glucose) reducing or non reducing?
Reducing
30
(Carbohydrates) Is sucrose (glucose and fructose) reducing or non reducing?
Non-reducing
31
(Carbohydrates) Is lactose (glucose and galactose) reducing or non-reducing?
Reducing
32
(Carbohydrates) Describe the test for non-reducing sugars.
- Complete Benedict’s test and if it stays blue (negative) - Boil with hydrochloridic acid for 5 mins then neutralise with alkali - Repeat Benedict’s test by heating at 90 degrees for 5 mins - Colour change from light blue to red/orange
33
(Carbohydrates) What are the features of starch in plants? (6)
- Consists of mainly the polysaccharide amylose - Storage polysaccharide for energy - Compact, good for storage - Coiled by hydrogen bonding within the chain - Insoluble (cell’s water potential/enzymes aren’t affected/cannot diffuse out of cells) - Hydrolysis of starch releases glucose for respiration to make ATP
34
(Carbohydrates) What are the biological roles of starch and glycogen? (3)
- Insoluble (doesn’t affect water potential) - Compact storage of chemical energy (many C-C, C-H bonds) - Branches in glycogen allow rapid enzymatic hydrolysis and release to glucose when required by amylase
35
(Carbohydrates) Describe hydrogen bonding between cellulose strands. (4)
- Each alternate beta-glucose unit is rotated 180 - Extensive hydrogen bonding can occur on either side of parallel chains - Forming microfibrils - layered to macrofibrils - layered to cellulose - Tensile / strong / fibrous polymer
36
(Carbohydrates) How does high tensile strength benefit cellulose, and what does this prevent?
Strength whilst remaining flexible which prevents osmotic lysis of plant cells.
37
(Carbohydrates) Describe a turgid cell.
Water enters by osmosis, vacuole swells and pushes against cell wall
38
(Carbohydrates) Describe flaccid cell.
Water lost from cell, vacuole shrinks, cell loses shape.
39
(Carbohydrates) Describe chitin polysaccharide.
Very tough with amino acids added, forming a mucopolysaccharide.