3.1.1-3 - Atomic Structure, AoS + Bonding Flashcards
what is meant by ‘electronegativity’?
ability of an atom to attract the electron density of a covalent bond towards itself
what happens to electronegativity down the group?
electronegativity decreases
- due to increased shielding, meaning the distance between the nucleus + outer electron is greater
what happens to electronegativity across the period?
electronegativity increases
- nuclear charge increases
what is meant by ‘polarity’?
unequal sharing of electrons in a bond
how do London forces arise?
- uneven distribution of electrons within an atom. This results in a slightly negative and slightly positive
charge on either side of the atom - induces a temporary dipole; temporary dipole induces other dipoles on a neighbouring atom/molecule
why is solid ice less dense than water?
- lattice structure of hydrogen bonds (very rigid + more stable)
- bonds push the water molecules further apart, which lowers the density
what’s the bond angle of a linear molecule and why?
180; 2 bonding pairs of electrons around the central atom which repel as far as possible equally
what’s the bond angle of a trigonal planar molecule and why?
120; 3 electron pairs around the central atom which repel as far apart as possible equally
what’s the bond angle of a tetrahedral molecule and why?
109.5; 4 electron pairs around the central atom which repel as far apart as possible equally
what’s the bond angle of a trigonal bipyramidal molecule and why?
120 + 90; 5 electron pairs around the central atom which repel as far apart as possible equally
what’s the bond angle of an octahedral molecule?
90; 6 electron pairs around the central atom which repel as far apart as possible equally
what’s the bond angle of a pyramidal molecule and why?
107; there are 3 bonding pairs and 1 lone pair of electrons around the central atom; lone pairs repel more than bonding pairs
what’s the bond angle of a non-linear molecule and why?
104.5; 2 bonding pairs and 2 lone pairs around the central atom - lone pairs repel more than bonding pairs
what is meant by ‘relative atomic mass’?
the weighted average mass of an atom of an element, relative to 1/12th the relative atomic mass of an atom of carbon-12
how do you prepare a standard solution?
- weigh the required mass of solid in a weighing boat using a balance
- transfer the solid into a beaker using distilled water to wash it out - preventing any solid remaining in the sample bottle
- reweigh the sample bottle and work out the difference
- add distilled water to the beaker to dissolve the solid (small volume of water) + use a stirring rod to stir
- transfer the dissolved solution into a 250cm3 graduated volumetric flask using a funnel, rinsing contents of the beaker and stirring rod with distilled water into the flask
- add more distilled water, fill up the solution to 250cm3, using a dropping pipette for the last few drops. making sure the bottom of the meniscus is touching the line marking 250cm3.
- invert the volumetric flask several times