3.1 Physical Chemistry: .7 Oxidation, reduction and redox reactions Flashcards

1
Q

what is oxidation?

A

the loss of electrons

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2
Q

what is reduction?

A

the gain of electrons

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3
Q

what is an oxidising agent?

A

atom/molecule that accepts electrons and gets reduced its self

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4
Q

what is an reducing agent?

A

atom/molecule that donates electrons and gets oxidised its self

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5
Q

what does the oxidation state of an element tell you?

A

-it tells you the total number of electrons it has donated or accepted

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6
Q

what are the oxidation states of elements?

A

0

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7
Q

what are the oxidation states of elements bonded to identical atoms?

A

0

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8
Q

what are the oxidation state of an overall compound?

A

the ion charge
e.g if has no charge the oxidation is 0
if it has a charge of -2 then the oxidation state is -2

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9
Q

what is the oxidation state of a simple monatomic ion?

A

it is the same as its charge

e.g Na+ would have oxidation state of +1

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10
Q

what is the oxidation state of elements in group 1 in a compound?

A

+1

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11
Q

what is the oxidation state of elements in group 2 in a compound?

A

+2

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12
Q

what is the oxidation state of elements in group 6 in a compound?

A

-2

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13
Q

what is the oxidation state of elements in group in group 7?

A

-1

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14
Q

what is the oxidation state of oxygen,

what are the exceptions?

A
  • the oxidation state of oxygen is -2
  • but when oxygen is in a peroxide it is -1 H2O2
  • when it is bonded with fluorine it is +2 e.g OF2
  • when its in O2F2 it is +1
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15
Q

what is the oxidation state of chlorine? what are the exceptions?

A
  • the oxidation state of Chlorine is -1

- BUT when it is bonded with Oxygen it is +1

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16
Q

what is the oxidation state of Hydrogen? what are the exceptions?

A
  • the oxidation state of Hydrogen is +1

- BUT when it is bonded with any element in group 1 it is -1

17
Q

what is the oxidation state of Cl in the Chlorate (I) ion (ClO-)

A

+1
because…
Cl O-
+1 -2= -1

18
Q

what does an increase in oxidation number mean?

A
  • it means that the chemical has gone through oxidation

- there has been a loss of electrons

19
Q

what does a decrease in oxidation number mean?

A
  • it means that the chemical has gone through reduction

- there has been a gain of electrons

20
Q

state whether this reaction is a redox reaction?

Zn + 2HCl –> ZnCl2 + H2

A

Zn + 2HCl –> ZnCl2 + H2
ox no of Zn= 0
ox no of H=+1
ox no of Cl= -1

ox no of Zn= +2
ox no of Cl= -1
ox no of H= O

Zn has gone up in oxidation number so it is oxidation
Hydrogen has gone down in oxidation number so it reduction.
Therefore this is a redox reaction.

21
Q

in this reaction state which is the oxidant and which is the reducing agent
Zn + 2HCl –> ZnCl2 + H2

A

H+ is the oxidant (it oxidised the Zn)

Zn is the reducing agent (it reduces the H+ ion)

22
Q

when balancing a combined ionic equation, what are the steps that you should follow?

A
  • work out the oxidation states of each element
  • work out the electrons
  • work out if there water molecules and H+ ions are required
  • balance the electrons