3. Arrangement Of Electrons Flashcards
Bohr passed light from a _______ through a prism to emit an emission spectrum.
Hydrogen Gas Discharge Tube
Spectrometers
Allow measurement of the frequency of each band of light
Spectroscopes
Allow the spectrum to be viewed only, not measured
Lithium flame test colour
Crimson
Potassium colour flame test
Lilac
Barium colour flame test
Green
Sodium (street lights) colour
Yellow
Energy level
Energy level is defined as the fixed energy value that an electron in an atom may have
Ground state
Ground state of an atom is one in which the electrons occupy the lowest available energy levels.
Excited state
Excited state of an atom is one in which the electrons occupy higher energy levels than those available in the ground state.
What is the name given to the visible light emitted in the emission spectrum?
Balmer Series: emission of visible light due to electrons falling to the n=2 energy level.
Why do different elements have different line spectra?
- Diff no. Of electrons
- Diff. Nuclear charge
- Diff electrostatic attractions resulting in diff. Electron transitions
Formula for emission spectrum
E2 - E1 = hf
H is Planck’s constant
Uses of an Atomic Absorption Spectrometer
Detecting presence and concentration of certain elements (lead, chlorine) dissolved in water.
Sublevel
Sublevel is a subdivision of a main energy level and consists of one or more orbitals of the same energy.
Who proposed the theory of electrons having a wave motion?
De Broglie
Heisenberg’s Uncertainty Principle
States that it is impossible to measure the velocity and position of an electron simultaneously .
3 limitations of Bohr’s theory
- only accounted for the emission spectrum of Hydrogen (simple case)
- didn’t take wave particle duality of electrons into account (el travel in precise paths)
- didn’t take existence of sublevels/orbitals into account
- Heisenberg in conflict w Bohr: can only refer to probability of an electron
Atomic orbital
A region in space around the nucleus where there is a high probability of finding an electron.