week 1 defs Flashcards
Exothermic
Heat is given out to the surroundings (the reactants lose energy)
Endothermic
Heat is taken in from the surroundings ( the reactants gain energy)
Activation energy
The minimum energy required to start a reaction by breaking the bonds
Standard conditions
A pressure of 100kpa, a stated temperature, usually 298K (25’C), and a concentration of 1 Mol dm-3 (for reactions with aqueous solutions)
Standard enthalpy change of reaction
the enthalpy change that acccompanies a reaction in the molar quantities expressed in a chemical equation (under standard conditions, all reactants and products in their standard states)
Standard enthalpy change of formation
the enthalpy change that takes place when one mole of a compound is formed from its constituent elements (in their standard states under standard conditions)
Standard enthalpy change of combustion
the enthalpy change that takes place when one mole of a substance reacts comletely with oxygen (under standard states under standard conditions)
Average bond enthalpy
the average energy change that takes place when breaking, by homolytic fission, 1 mol of a given type of covalent bond by the molecules of a gaseous species
Enthalpy change of neutralisation
The energy change that accompanies the neutralisation of an aqueous acid by an aqueous base to form one mole of a gaseous species
Catalyst
speeds up a reaction without being consumed by the overall reaction
Dynamic equilibrium
the equilibrium that exists in a closed system when the rate of the forward reaction is equal to the rate of the reverse reaction
Le Chatelier’s principle
when a system in dynamic equilibrium is subject to change, the position of equilibrium will shift to minimize the change