24.25 thermodynamics Flashcards
1
Q
Diathermic
A
exchanges heat
2
Q
Adiabatic
A
Doesn’t exchange heat
3
Q
3 components of standard internal energy
A
- vibrational and rotational kinetic E
- Translational kinetic E
- Potential E from intermolecular forces
4
Q
Entropy
A
a measure of the number of ways microstates of a system in thermodynamic equilibrium can produce the same macrostate
5
Q
Isobaric
A
constant pressure
6
Q
Isochoric
A
constant volume
7
Q
Isothermic
A
constant temperature
8
Q
Steady state
A
constant internal energy
9
Q
Hemholtz free energy
A
energy required to create a system - energy that is given from the environment
10
Q
Hemholtz free energy equation
A
F = U - TS
11
Q
Enthalpy
A
Energy required to create a system + energy required to create room for it
12
Q
Enthalpy equation
A
H = U + pV
13
Q
GIbbs free energy
A
Total energy required to create a system and make room for it, minus the energy we receive from the environment
14
Q
Gibbs equation
A
G = U + pV - TS
