2.2.2 Flashcards
Ionic compounds properties GIS
High melting & boiling points
Strong electrostatic forces - large amounts of energy needed to break
Electrostatic forces - hold opposite charged ions together , why ionic compounds have high mp & bp
Electrical conductivity GIS
Ions in fixed position, cannot move
Non-conductor of electricity
Electrical conductivity when melted or dissolved in water GIS
Solid lattice breaks down & ions free to move
Ionic compound now a conductor of electricity
GIS solubility
Dissolves in polar solvents (e.g. water)
Polar water molecules break down lattice by surrounding each ion to form a solution
Giant ionic lattice
Solid ionic compound exist as giant ionic lattices
Strong electrostatic attraction between opp charged ions result in a high melting point
Polyatomic ions
E.g. OH-, SO42-
Have covalent bonds within polyatomic ons
Form ionic bonds with other ions
Ionic bonding strongest
When one/both ions have a high charge and are small
MgO > NaCl as Mg=2+, O=2-
2 non-metals
Covalent bonding
Metal + non-metal
Ionic
Noble gases
Stable electron configuration
Full outer shell so, very stable
Covalent bonding
Strong electrostatic attraction between a shared pair of electrons and the nuclei of the bonded atoms
Double bond
Triple bond
2 shared pairs of electrons
3 shared pairs of electrons
Dative covalent bonding (co-ordinate bonding)
One of the atoms supplies both the shared electrons for the covalent bond
E.g. ammonium ion, NH4+
Nitrogen atoms donates a pair of electrons to a proton (H+ ion)
Average bond enthalpy
Energy needed to break one mole of a particular bond
Always exothermic
Larger the value of the bond enthalpy, the stronger the covalent bond
Ions
An atom may become charged when the number of electrons is altered (loss or gain of electrons)
This charged atom is called an ion