2.2 Reaction feasibility Flashcards

1
Q
A
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2
Q

Standard enthalpy of formation

A

The enthalpy change when one mole of a substance is formed from its elements in their standard states

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3
Q

The enthalpy change when one mole of a substance is formed from its elements in their standard states

A

Standard enthalpy of formation

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4
Q

when is a substance in its standard stare

A

Pressure of 1 atmosphere

And at a specific temperature, usually 298 K

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5
Q

What can standard enthalpy of a reaction be calculated from

A
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6
Q

Entropy of a system

A

A measure of the degree of disorder of the system

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7
Q

A measure of the degree of disorder of the system

A

Entropy of a system

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8
Q

Entropy symbol

A

S

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9
Q

The greater the degree of disorder, the _____ the entropy

A

Greater

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10
Q

The _________ the degree of disorder, the greater the entropy

A

Greater

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11
Q

The greater the _____________, the greater the entropy

A

degree of disorder

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12
Q

The greater the degree of disorder, the greater the ______

A

Entropy

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13
Q

Solids have ____ disorder

A

Low

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14
Q

______ have low disorder

A

Solids

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15
Q

Gases have _____ disorder

A

High

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16
Q

Entropy when temperature increases

A

Increases

17
Q

Entropy at the MP of a substance

A

Rapid increase in entropy

18
Q

When is there a rapid increase in entropy of a substance

A

At the MP

19
Q

Entropy at boiling point

A

More rapid and larger change in entropy

20
Q

When is there a more rapid and larger change in entropy

A

Entropy at boiling point

21
Q

Second law of thermodynamics

A

The total entropy of a reaction system and its surroundings increases the entropy of the surroundings

22
Q

The total entropy of a reaction system and its surroundings increases the entropy of the surroundings

A

Second law of thermodynamics

23
Q

Heat energy released by the reaction system affect on surroundings

A

Increases the entropy of the surroundings

24
Q

What increases the entropy of the surroundings

A

Heat energy released by the reaction system

25
Q

What decreases the entropy of the surroundings

A

Heat energy absorbed by the reaction

26
Q

Heat energy absorbed by the reaction system affect on surroundings

A

Decreases the entropy

27
Q

Third law of thermodynamics

A

Entropy of a perfect crystal at 0 K is zero

28
Q

Entropy of a perfect crystal at 0 K is zero

A

Third law of thermodynamics

29
Q

Free energy

A

G

30
Q

Change in free energy between reactants and products is negative, what is said about the reaction

A

Reaction may occur. The reaction is feasible

31
Q

Enthalpy of a feasible reaction

A

Change in free energy between reactants and products is negative

32
Q

Feasible reaction

A

A reaction that tends towards the products rather than the reactants

33
Q

A reaction that tends towards the products rather than the reactants

A

Feasible reaction

34
Q

Rate of reaction of feasible reaction

A

No indication

35
Q

If G > 0, reaction may be _______

A

Feasible

36
Q

Delta G at equilibrium

A

0

37
Q

When will a reversible reaction proceed to

A

Will proceed spontaneously until the composition is reached where delta G = 0

38
Q

Feasibility of reactions under non standard conditions

A

Any reaction is feasible if delta G is negative

39
Q
A