2.2 amount of substance Flashcards

1
Q

charge of Zn and Ag

A

Ag+
Zn 2+

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2
Q

water of crystallisation

A

water molecules that exist in crystal structures
for every mole of salt, you have a certain number of moles of water of crystallisation
written as: .xH2O

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3
Q

salts are ionic compounds which can be hydrated or anhydrous
what is the connection with the salts and water?

A

water is polar and is attracted to ions in a salt
δ- oxygen is attracted to positive ions
δ+ hydrogen is attracted to negative ions

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4
Q

experiment to work out value of crystallisation

A

1.heat hydrated salt to remove water of crystallisation leaving behind anhydrous salt
2. hydrated mass - anhydrous mass = mass of water
3. work out moles of anhydrous salt and water
4. divide both mole values by smallest mole value to work out ratio of (salt : water)

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5
Q

ionic equation of:
H2SO4 + 2KOH -> K2SO4 + 2H2O

A

(2H+) + (SO4 2-) + (2K+) + (2OH-) -> (2K+) + (SO4 2-) + (2H2O)
CANCEL ions that appear on both sides

2H+ + 2OH- -> 2H2O
*final ionic equation charges must balance

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6
Q

spectator ions

A

ions that do not get involved in reaction

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7
Q

Avagadro’s number

A

6.02 x 10^23

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8
Q

calc number of particles/molecules

A

no. of particles = Avg number x moles

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9
Q

calc number of moles (mass and Mr)

A

moles = mass/Mr

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10
Q

calc number of moles (conc and vol)

A

moles = conc (moldm-3) x vol (dm3)

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11
Q

ideal gas equation

A

pV = nRT

p - pressure (Pa)
V - volume (m3)
n - moles
R - gas constant (8.31 JK-1mol-1)
T - temperature (K)

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12
Q

standard conditions

A

298K
100 kPa

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13
Q

m -> dm -> cm
m2 -> dm2 -> cm2 (area)
m3 -> dm3 -> cm3 (volume)

A

x10 x10
x100 x100
x1000 x1000

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14
Q

empirical formula

A

the simplest whole number ratio of elements in a compounde

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15
Q

percentage yield

A

percentage yield = (actual yield/theoretical yield) x 100

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16
Q

what is theoretical yield?

A

the amount of a product produced assuming no products are lost and all reactants react fully

17
Q

atom economy

A

how efficient a reaction is

% atom economy = (molecular mass of desired product/sum of Mr of all products) x100

18
Q

importance of economy

A
  • high atom economies produce less waste, benefit environment
  • high atom economies means raw materials are used more efficiently, sustainable
  • companies try to use reactions closer to 100% atom economy
  • higher atom economy means less by-products, less time and money spent separating these from desirable product