2.2/3 (Spec) Flashcards
Electron
Relative charge -1
Relative mass 1/1836
Orbit nucleus in shells
Proton
Relative charge +1
Relative mass 1
Found in nucleus
Neutron
Relative charge 0
Relative mass 1
Found in nucleus
Isotope
Equal atomic number of stable isotope
Different mass number than stable isotope
Relative isotopic mass
Mass of one atom of an isotope relative to 1/12th the mass of one atom of carbon-12
Relative atomic mass
Weighted mean average of relative isotopic masses of all isotopes of an element relative to one atom of carbon-12
Mass spectrometry function, process
Placed in spectrometer
Vapourised and ionised - positive ions
Ions accelerated - heavier ions - low speed
- lighter ions - high speed
Ions separated on speed/mass
Ions detected on mass spectrum as mass : charge (m/z)
High abundance, high signal
Ionic charge
Group # = # valence electrons Group 1 - 1+ ionic charge Group 2 - 2+ ionic charge Group 3 - 3+ ionic charge Group 5 - 3- ionic charge Group 6 - 2- ionic charge Group 7 - 1- ionic charge Zn2+ and Ag+ break this rule!
State symbols
(g) - gaseous state
(l) - liquid state
(aq) - dissolved in aqueous solution
(s) - solid state
Polyatomic ions
Ammonium (NH4)+ Hydroxide (OH)- Nitrate (NO3)- Nitrite (NO2)- Hydrogencarbonate (HCO3)- Manganate (VII) (MnO4)- Carbonate (CO3)2- Sulfate (SO4)2- Sulfite (SO3)2- Dichromate (VI) (Cr2O7)2- Phosphate (PO4)3-
Avogadro constant
6.02 x 10^23 # of particles in one mole of carbon-12
Ideal gas equation
pV = nRT p = pressure (Pa) V = volume (m^3) n = moles (mol) R = ideal gas constant (8.314jK^-1mol^-1) T = temperature (K)
Concentration equation
moles/volume (dm^3)
Percentage yield equation
actual yield/theoretical yield x 100%
Atom economy equation
Mr(desired product)/Sum(Mr(All reactants) x 100%