2.1.5 Redox Flashcards
What is an oxidation number ?
the total number of electrons that an atom either** gains or loses** in order to form a chemical bond with another atom.
It is a + or - sign followed by a number
(total number of electrons lost or gained by an atom in a compound)
Rule for oxidation number in elements
Oxidation **number of 0 **
(H2 = 0, Ca = 0)
Rule for oxidation numbers in monoatomic ions
Oxidation number is the same as the ionic charge
(Zn 2+ = +2)
Rule for oxidation number in polyatomic ions
**Sum **of the individual oxidation numbers = overall charge on the ion
Rule for oxidation number in a neutral compound
Sum of oxidation numbers = 0
Oxidation number of fluorine (IN A COMPOUND)
-1
This is the most electronegative element
Oxidation number of oxygen
(In a compound)
-2
-Bonded to flurorine = +2
-In a peroxide = -1
Oxidation number of hydrogen
(In a compound)
+1
(Unless bonded to a metal - metal hydride- then it is -1)
This is because** hydrogen only has one electron** so it can either lose the electron to a non metal and gain a positive charge, or** it can gain an electron** from a metal and gain a negative charge
Oxidation number of chlorine
(In a compound)
-1
What do roman numerals show ?
They show the oxidation number of variable elements
Define redox reaction
A reaction involving reduction and oxidation
(They always occur together)
Define oxidation and reduction in terms of electrons
Oxidation = loss of electrons
Reduction = gain of electrons
(Total electrons lose = Total electrons gained)
OILRIG (Oxidation is loss, reduction is gain)
Define oxidation and reduction in terms of oxidation number
Oxidation = increased oxidation number
Reduction = decreased oxidation number
(Total increase in oxidation no. = Total decrease in oxidation no. - They must balance)
In a redox reaction, what type of elements typically gain electrons, and which donate electrons ?
Metals = lose electrons (to become positive ions)
Non-metals = gain electrons (to become negative ions)