2.1.3 Amount of Substance Flashcards
What is amount of substance?
Number of particles in a substance
Mass, moles and molar mass equation?
n = m/mr
mr no mr
Avogadro’s constant equation?
n = no. of particles/ avo.
What is molar mass? Unit?
Mass (g) per mole of a substance
gmol-1
What is molecular formula?
No. and type of atoms of each element in a molecule
What is empirical formula?
Simplest whole number ratio of atoms of each element in a compound
Why is empirical formula useful?
Giant crystalline structure- molecular would be in millions, e.g NaCl
What is relative molecular mass?
Mass of a simple molecule relative to the mass of an atom of C-12
How do you calculate relative molecular mass?
Add up relative atomic masses of each element in periodic table
What is relative formula mass?
Mass of giant structures relative to the mass of an atom of C-12
How do you calculate empirical formula from data?
- Convert into moles
2. Divide by smallest whole number
How do you calculate molecular formula from data?
- Convert into moles (% treated like mass)
- Find empirical
- Find relative mass (add up all atomic masses from PT)
- Mass of compound/ relative mass of empirical to find scale factor
- Empirical x Scale factor
What is a hydrated salt/ water of crystallisation?
A crystalline structure that contains water
What is an anhydrous salt?
A crystalline structure that does not contain water
Method to determine the water of crystallisation in hydrated salts?
- Weigh crucible
- Add salt- weigh
- Heat for 5 mins
- Cool- weight
5 Calc. moles of anhydrous salt - Calc. moles of water
- Find empirical formula of salt:water
Flaws in the method of determining the water of crystallisation in hydrated salts?
- Not all water has been lost- heat to constant mass
2. Salts can decompose to diff. salts
How do you convert from dm3 to cm3?
Dm3 x 1000 = cm3
Cm3 / 1000 = dm3
What is concentration? Units?
Amount of solute, in moles or grams, dissolved in each 1dm3 of solution
moldm-3 or gdm-3
What is a standard solution?
Solution of known concentration and volume
Moles, concentration, volume equation?
n = c x v
no more caravans
What is molar gas volume? Units?
Volume per mole of gas molecules at a known temp and pressure
dm3mol-1
What is room temperature and pressure that most experiments are set in?
T: 20C
P: 101kPa
Vol of gas, moles and molar gas vol equation?
Vol of gas = moles x 24 (if RTP)
Vol of gas = moles x molar volume
What is the ideal gas equation?
pV = nRT
Units of ideal gas equation?
Pressure = Pa Volume = m3 Moles = mol Temp = K
What is stoichiometry?
Balanced ratio of moles in an equation
What is theoretical yield?
Max. possible amount of product produced from a reaction
What is actual yield?
The actual amount of product produced from a reaction (actual
What is percentage yield?
How much of the theortical yield you made (%)
What is the percentage yield calculation?
(Actual/theoretical)x100
What is a limiting reagent?
Reactant not in excess and will be used up first and stop the reaction
What is atom economy?
How well atoms have been utilised in a chemical equation
What is the atom economy calculation?
Atom ec. = total molar masses of desired products/ total molar masses of all products