2.1-2.9 Flashcards

1
Q

define ionic bond

A

the electrostatic attraction between oppositely charged ions. mostly happens between metals and non-metals

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2
Q

what are the 6 main molecular ions?

A
hydroxide: OH^-
nitrate NO3 ^-
sulphate: SO4 ^2-
Carbonate: CO3 ^2-
hydrogen carbonate: HCO3 ^-
Ammonium: NH4 ^+
Phosphate- PO4 ^3-
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3
Q

how to draw a dot and cross diagram for ionic compounds

A

the symbol goes in the centre,
draw the outer shell with dots and crosses
put in a bracket with the charge by the top right corner
and the ratio number next to the bottom right corner

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4
Q

define: coordination number

A

the number of oppositely charged ions surrounding one ion in an ionic lattice structure

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5
Q

explain the M.P of ionic compounds

A

they have strong electrostatic forces of attraction which require lots of energy to break.

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6
Q

explain the strength of ionic compounds

A

they are very brittle. any dislocation causes alike charges to be next to each other. these repel causing a fracture

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7
Q

explain the solubility of ionic compounds

A

only soluble in polar solvents. Solubility depends on the balance between the attraction of the oppositely charged ions to each other and the attraction of the separate ions to the solvent

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8
Q

explain the conductivity of ionic compounds

A

only conductive when aqueous of molten. the ions need to be free to move but they are stuck in place when solid

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9
Q

define covalent bond

A

the electrostatic force of attraction between the nucleus and the shared pair of electrons. only happens between non-metals

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10
Q

define hybridisation

A

when atoms move electrons to an unoccupied orbital in the same energy level to form more covalent bonds

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11
Q

what is a dative covalent bond?

A

when one atom donates both electrons in a covalent bond.

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12
Q

explain the m.p of simple molecules

A

it intermolecular forces are weak so very little energy is needed to separate the molecules

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13
Q

explain the conductivity of simple molecules

A

they don’t conduct electricity because there are no free ions or electrons

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14
Q

explain the solubility of simple molecules

A

depends on the polarity. tend not to be soluble in water

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15
Q

define electronegativity

A

a measure of the attraction between a bonded atom and the pair of electrons in the covalent bond

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16
Q

factors affecting electronegativity

A

nuclear charge- higher charge causes a stronger
attraction
atomic radius- closer to the nucleus causes a stronger
attraction
shielding- more shielding causes more repulsion so
the attraction is weaker

17
Q

how does electronegativity change down a group and why

A

it decreases. the atomic radius and shielding increases. this causes a weaker attraction to the bonding electrons

18
Q

how does electronegativity change across a period

A

it increases. the atomic radius decreases and the nuclear charge increases. this causes a stronger attraction to the bonding electrons.

19
Q

whats a metallic bond

A

the electrostatic force of attraction between metal cations and a sea of delocalised electrons.

20
Q

explain the density of metals

A

they have a higher density. this is because the cations are packed together tightly

21
Q

explain the M.P of metals

A

it’s very high. the attraction between cations and sea of electrons is very strong so lots of energy is required

22
Q

explain the solubility of metals

A

they are insoluble. the attraction between metal cations and electrons is much stronger than the attraction between water and metal cations

23
Q

how does the M.P of metals change across a period

A

its increases due to the atomic radius decreasing and the number of delocalised electron per atom increasing. the strength of attraction between electrons and metal cations increases so more energy is needed.

24
Q

how does the M.P of metals change down a group

A

it decreases due to the atomic radius and shielding increasing. this makes the attraction weaker so less energy is required.

25
Q

explain the conductivity of metals

A

they are great electrical conductors. the delocalised electrons are free to move through the lattice. the more outer electrons a metal has the better conductor it is

26
Q

define ductile

A

can be drawn into a wire

27
Q

define malleable

A

can be hammered into shape

28
Q

explain why metals are malleable

A

the layers of cations can easily slide over each other without disrupting the forces of attraction between the cations and electrons.

29
Q

what are crystals

A

solids in which the particles are in a regular lattice or arrangement held together by forces of attraction

30
Q

what are the types of crystal

A

ionic,
metallic,
giant covalent,
simple molecular

31
Q

explain the properties of simple molecules

A

low M.P- weak intermolecular forces
soft- weak intermolecular forces
brittle- movement disturbs the forces of attraction
insulators- no charged particles to carry a charge

32
Q

properties of diamond

A

very hard,
insulator,
insoluble,
very high M.P

33
Q

properties of graphite

A

soft,
conductor,
insoluble,
very high M.P

34
Q

properties of graphene

A

conductor,
very high M.P,
insoluble,
strong