2. Chirality Flashcards

1
Q

what is stereoisomerism

A

same molecular formula
atoms are arranged in the same way
different orientation of their bonds in space

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2
Q

what is a chiral (or asymmetric) carbon atom

A

carbon atom which has 4 different groups attached to it

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3
Q

on a chiral carbon it is possible to arrange the groups in 1.__ different ways around the carbon atom
so that 2.__ different molecules are made.
3.what are these molecules called?

A
  1. 2
  2. 2
  3. enantiomers or optical isomers
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4
Q

what are enantiomers/optical isomers

A

mirror images of eachotehr that cant be superimposed

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5
Q

if a molecule can be superimposed on its mirror image it is

A

achiral

doesn’t have an optical isomer

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6
Q

optical isomers are optically active which means

A

they rotate plane-polarised light
one enantiomer rotates it in a clockwise direction the other rotates it the same amount byt in an anticlockwise direction.
sometimes identified as the D isomer or the L isomer

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7
Q
  1. you usually only ever find __ of the enantiomers

2. 2 e.g’s

A
  1. 1
  2. all naturally occurring amino acid are L-amino acids.
    most sugars are D-isomers
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