2 - Atomic Structure Flashcards
mass spectrometer
used to determine the relative atomic mass of an element from its isotopic composition by deflecting positive charged gaseous ions using an electric or magnetic field
relative atomic mass
weighed mean of the naturally occurring isotopes of the element relative to 1/12 of carbon-12
emission spectra at n=1
Lyman series - produces ultraviolet light. higher energy, shorter wavelength, higher frequency
emission spectra at n=2
Balmer series - the visible part of the spectrum
emission spectra at n=3
Paschen Series - produces infrared light. lower energy, loader wavelength, shorted frequency
how does hydrogen give evidence that for the existence of electrons in discrete energy levels, which converge at higher energies.
hydrogen has an emission spectrum in the paschen, Balmer and Lyman regions. the visible end of the emission spectrum converges towards higher frequencies of the blue light. electron fall to n=1 uv light is emitted, at n=3, ir light is emitted.
orbital
2 electrons that spin in opposite directions
continuous spectrum
only all the colours
line spectrum
black with lines of colour seen. the lines allow the continuous spectrum to energy
converging towards (in terms of emission spectrum)
what direction the lines on the line spectrum move closer together
Pauli Exclusion
two electrons per orbital that spin in opposite direction
Aufbau Principle
fill the sub-shells from lowest energy increasing
Hund rule
‘bus seating’ half full sub shell before pairing electrons