13 - The periodic table - the transition metals Flashcards
oxidised
when there is an increased oxidation number of an element in a reactions
reduced
decrease of oxidation number
Haber Process (and catalyst)
N2 (g) + 3H2(g) -> 2NH3(g) (catalyst is Fe(s)
Decomposition of hydrogen (and catalyst)
2H2O2(aq) ->n 2H2O + O2 (catalyst is MnO2(s)
Ligands
ligands are natural molecules or ions that Havel at least one non-bonding pair of electrons that form coordinate bonds with the d-orbitals of transition elements. Both electrons that are shared belong to the ligand. transition metals form complex ions with ligands
monodentate
one coordinate bond formed
polydentate
more than one coordinate bond formed
ferromagnetism
magnetism due to unpaired electrons mainly in Fe (also cobalt and nickel), when there is a magnetic field
Paramagetism
magnetism due to unpaired electrons in the presence of a magnetic field. The more unpaired electrons the stronger the paramagnetism
diamagnetism
electrons of the transition metal in the complex ion are all paired. has the characteristic of repelling magnetic fields
transition metals
metals with and incomplete d-orbital in one ore more oxidation state
factors effecting colour of transition metals (3)
identity of transition metal, oxidation number, identity of ligand