13 - The periodic table - the transition metals Flashcards

1
Q

oxidised

A

when there is an increased oxidation number of an element in a reactions

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2
Q

reduced

A

decrease of oxidation number

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3
Q

Haber Process (and catalyst)

A

N2 (g) + 3H2(g) -> 2NH3(g) (catalyst is Fe(s)

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4
Q

Decomposition of hydrogen (and catalyst)

A

2H2O2(aq) ->n 2H2O + O2 (catalyst is MnO2(s)

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5
Q

Ligands

A

ligands are natural molecules or ions that Havel at least one non-bonding pair of electrons that form coordinate bonds with the d-orbitals of transition elements. Both electrons that are shared belong to the ligand. transition metals form complex ions with ligands

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6
Q

monodentate

A

one coordinate bond formed

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7
Q

polydentate

A

more than one coordinate bond formed

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8
Q

ferromagnetism

A

magnetism due to unpaired electrons mainly in Fe (also cobalt and nickel), when there is a magnetic field

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9
Q

Paramagetism

A

magnetism due to unpaired electrons in the presence of a magnetic field. The more unpaired electrons the stronger the paramagnetism

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10
Q

diamagnetism

A

electrons of the transition metal in the complex ion are all paired. has the characteristic of repelling magnetic fields

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11
Q

transition metals

A

metals with and incomplete d-orbital in one ore more oxidation state

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12
Q

factors effecting colour of transition metals (3)

A

identity of transition metal, oxidation number, identity of ligand

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