2. Atomic Bonds Flashcards

1
Q

FLOWCHART: Sub-atomic structure defines _____, which defines ____ and ____.

A

Atomic bonds, which defines basic mat properties as well as material types.

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2
Q

Atomic packing is modified by ____

A

Packing defects

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3
Q

What two things define microstructure?

A

Atomic packing and packing defects.

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4
Q

Materials Processing techniques controls what two things?

A

Packing defects and macroscopic defects

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5
Q

What gives “actual material properties”

A

atomic packing and packing defects, modded by macroscopic defects.

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6
Q

What defines ideal material properties?

A

Microstructure does.

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7
Q

What are two ways to control atomic defects and macroscopic defects?

A

Materials processing techniques, as well as component production techniques (i.e. machining can improve surface finish)

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8
Q

What are the ICME scales?

name five

A
Electronic
Nano 
Micro (microstructure)
Meso (microstructure)
Macro
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9
Q

BONDING

What is a material?

A

A group of atoms, bonded together, used as a material

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10
Q

Why do atoms group together?

A

Atoms group together to minimize energy.

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11
Q

What is the ground state?

A

The lowest energy state of ONE atom

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12
Q

When is ground state achieved?

A

when the outermost shell is filled

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13
Q

What is a stable electron configuration?

A

Outermost shells are filled. i.e. noble gases.

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14
Q

What do you call an atom with a slight excess of electrons?

A

Metallic or electropositive.

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15
Q

What do you call an atom with a slight deficiency of electrons

A

Nonmetallic or electronegative.

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16
Q

Compare and contrast ground state and stable electron configuration.

A

They both describe the lowest energy state. Ground state is for ONE atom, S.E.C. is for a GROUP of atoms.

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17
Q

How does the ground state and stable electron configuration differ for noble gases

A

for noble gases they are the same.

18
Q

HOW DO ATOMS BOND

A

By coulombic forces

19
Q

What are coulombic forces?

A

Forces created between charged particles: repulsive if they’re charged the same way

20
Q

How are these coulombic forces created?

A

By creating a stable electron configuration

21
Q

How does ionic bonding happen?

A

Metal gives an electron to the non-metal. Coulombic forces keep the two ions attracted.

22
Q

Is ionic bonding directional?

A

No - forces are always attractive

23
Q

Metals, polymers, ceramics: which one performs ionic bonding?

24
Q

Up/down and left/right: which directions increase electronegativity?

A

UP, RIGHT increasing EN.

Electropositive: excess of electrons

25
RANDOM FACT
Ionic bonding creates compounds (i.e. ceramics)
26
Why do Ca or K not bond ionically?
Well, neither Ca or K can gain electrons. They can only give.
27
When does ionic bonding occur?
When electronegativities are far apart.
28
COVALENT BONDS SECTION
Yay!
29
When does covalent bonding happen?
Between super electronegative atoms.
30
What elements are considered non-metallic?
The noble gases, fluorides, H, and NOPS.
31
What elements are considered intermediate?
(think of semiconductors. B, C, Si, Ge, As, Se, Te
32
How do covalent bonds work?
At the point of shared electrons, there is an electron "cloud" that attracts the two nuclei.
33
Are covalent bonds directional?
Yes, they are.
34
Can a material have a mix of ionic and covalent bonds?
Yes! It's termed "ionic character". Increasing differences in electronegativity results in increasing ionic character, and thus an increase in ionic bonding. There are equations.
35
METALLIC BONDINGS
Yay!
36
Why does metallic bonding happen?
The atoms involved in metallic bonding are too polite - they readily give up all their electrons. Leads to a sea of delocalized electrons moving amongst metal ions.
37
What are secondary or van der vaals bonds?
If the electrons and protons are separated, dipoles form. These attract other dipoles
38
When are van der waals bonds important?
they're important when not obscured by a strong primary bond (i.e. ionic or metallic).
39
What can van der waals bonds determine?
Things like the solidification point of gases.
40
Van der waals are important for plastics!
Yeah! Plastics are weakish because of these van der waals forces
41
How do dipoles form?
1) Moving electrons Can condense inert gases!
42
Why does liquefaction occur at certain temperatures?
Because it just so happens to be the arrangement of lowest energy.